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C−C bond formation between a) an imine and an allyl compound catalysed by NaHMDS; b) styrene and an allyl compound catalysed by LDA; c) an aldehyde and toluene by activation of the benzylic group through cation–π interaction; d) conversion of benzaldehyde into N‐(trimethylsilyl)benzaldimine by NaHMDS.
