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. 2021 Jan 19;60(21):11628–11686. doi: 10.1002/anie.202006988

Scheme 13.

Scheme 13

Bimolecular mechanism for the reductive disproportionation of CO2 to CO and CO3 2− by active species of the type [Re(bpy)(CO)3] as proposed by Kubiak and co‐workers. Adapted with permission from ref. [137b]. Copyright 2014 American Chemical Society.