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. 2021 Jan 19;60(21):11628–11686. doi: 10.1002/anie.202006988

Scheme 32.

Scheme 32

Reductive adsorption of [Ni(cyclam)]+, oxidative desorption, and possible connection with the catalytic reduction of CO2 at mercury electrodes in solutions of [Ni(cyclam)]+ proposed by Balazs et al. [285] (cyclam*=form of the coordinated ligand that produces the more easily reduced [Ni(cyclam*)]2+).