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. 2021 May 14;27(34):8832–8845. doi: 10.1002/chem.202101229

Table 1.

31P NMR chemical shift assignments of the signals in the free ds6 or ds10 duplex and in their complexes with (±)‐trans‐δ‐viniferin.[a,b] |Δδ|≥0.10 are highlighted in bold.

ds6

Δδ[c]

ds10

Δδ[c]

C1pG2

−0.35

0.00

A1pA2

−0.65

+0.04

G2pT3

−0.70

0.00

A2pG3

−0.38

−0.07

T3pA4

−0.40

0.00

G3pA4

−0.50

0.00

A4pC5

−0.50

−0.01

A4pA5

−0.80

−0.05

C5pG6

−0.22

−0.02

A5pT6

−0.80

0.10

T6pT7

−0.57

−0.07

T7pC8

−0.40

+0.03

C8pT9

−0.50

0.00

T9pT10

−0.40

−0.05

[a] Measured at 15 °C in H2O/D2O (9 : 1), 100 mM NaCl, 10 mM sodium phosphate buffer (pH 7.0) and R=2.0. [b] Measured in ppm from external DSS. [c] Δδ=δbound‐δfree.