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. 2021 May 14;27(34):8804–8810. doi: 10.1002/chem.202100663

Scheme 3.

Scheme 3

One‐pot synthesis of the tetrahedral hetero‐pnictogen complexes 15. Top: using NaPH2 for the synthesis of 1 leading to HCl evolution in the second reaction step; bottom: using ME(SiMe3)2 (M=Li, K; E=P, As, Sb, Bi) for the synthesis of 15, which avoids HCl elimination resulting in higher yields.