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. 2021 Mar 10;14(8):1781–1804. doi: 10.1002/cssc.202100159

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© 2021 The Authors. ChemSusChem published by Wiley-VCH GmbH

This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.

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Scheme 10 — Enzyme‐catalyzed CO₂ fixation linked to chemical derivatization of the carboxylate product. (a) A strategy applying quaternary ammonium salt to shift the reaction equilibrium towards 1,6‐DHBD_Rs‐catalyzed carboxylation of resorcinol. The carboxylation step is linked to the precipitation of the carboxylate in one pot. The product was recovered by acid hydrolysis. 1,6‐DHBD_Rs=1,6‐dihydroxybenzoic acid decarboxylase. ^[100] (b) Pyruvate:ferredoxin oxidoreductase (PFOR)‐catalyzed CO₂ fixation linked with derivatization using semicarbazide. ^[107]