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Reaction schemes for the syntheses of PTX-CPPs. (A) The synthesis of PTX-LMWP. (B) The synthesis of PTX-TAT. (I) Succinic acid, DIPEA, DCM, RT, 12 h. (II) EDC, NHS, DIPEA, LMWP, RT, DMSO, 24 h. (III) Succinic anhydride, DIPEA, DCM, RT, 12 h. (IV) EDC, NHS, DIPEA, N-(2-aminoethyl) maleimide, DMSO, RT, 12 h. (V) TAT, DMSO, RT, 1 h.
