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. Author manuscript; available in PMC: 2022 Jun 23.
Published in final edited form as: J Am Chem Soc. 2021 Jun 10;143(24):9191–9205. doi: 10.1021/jacs.1c04155

Table 1.

Quantum Yields of Ligand Exchange (ΦLE) and Singlet Oxygen (ΦΔ) Production for 7–11

complex ΦLEa ΦΔb
7 0.15(1)c
7 0.31(1)
8 0.13(2)
9 0.024(4) 0.59(6)
10 0.014(3) 0.57(6)
11 0.061(8) 0.80(7)
[Ru(tpy)(Me2dppn)(L)]2+ d 0.073(1) 0.57(7)
a

In CH3CN, λirr = 500 nm, N2 atmosphere.

b

In MeOH, λirr = 460 nm, determined with diphenylisobenzofuran (DPBF) 1O2 probe.

c

In H2O, λirr = 500 nm.

d

From ref 72; L = imatinib.