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. 2021 Jul 9;12:4243. doi: 10.1038/s41467-021-24501-1

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© The Author(s) 2021

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

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Fig. 1 — a A donor-acceptor (DA) unit with a large torsional angle φ is covalently incorporated into a polymer chain. b Stretching of the polymer backbone causes a decrease of φ. c Schematic reversible shift of the UV-vis-absorption band as a response to elongational stress. d Structure of the DA-system reported here based on diphenyldiketopyrrolopyrrole (PhDPP).