Table 1.
The conditions under which the polymerizations of AzoAA and AzoMA were performed.
Polymerization* | M/I/CuX/L | Catalyst | Ligand | Initiator | Solvent | Temp. | Time |
---|---|---|---|---|---|---|---|
(°C) | (h) | ||||||
1A | 50:1:1:1 | CuCl | PMDTA | ECP | Dioxane | 65 | 24 |
2A | CuCl | ECP | 65 | 48 | |||
3A | CuCl | ECP | 65 | 72 | |||
4A | CuCl | ECP | 65 | 96 | |||
5A | CuBr | EBriB | 95 | 48 | |||
6A | CuBr | EBriB | 95 | 72 | |||
1M | 50:1:1:1 | CuBr | PMDTA | EBriB | Dioxane | 95 | 24 |
2M | 48 | ||||||
3M | 72 | ||||||
4M | 96 | ||||||
5M | 120 | ||||||
6M | 132 | ||||||
7M | 100:1:1:1 | CuBr | PMDTA | EBriB | Dioxane | 95 | 48 |
8M | 72 | ||||||
9M | 96 | ||||||
10M | 120 | ||||||
11M | 144 | ||||||
12M | 50:1:1:1 | CuBr | PMDTA | EBriB | Anisole | 120 | 24 |
13M | Me6TREN | 28 | |||||
14M | Me6TREN | 48 |
* Polymerizations of AzoAA are denoted as A; polymerizations of AzoMA are denoted as M.