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. 2021 Jun 27;26(13):3927. doi: 10.3390/molecules26133927

Table 2.

Identification of flavones in hairy roots S. baicalensis, S. lateriflora, S. przewalskii and S.pycnoclada by HPLC-MS/MS.

Compounds Molecular Mass MRM Transition, m/z
1 baicalin 446 447.1 → 271.1
2 wogonoside 460 461.1 → 285.1
3 baicalein 270 271.1 → 123.1
4 wogonin 284 285.1 → 270.1
5 chrysin 254 255.1 → 153.1
6 * chrysin-6-C-β-d-glucoside 416 417.1 → 281.1
7 * chrysin-8-C-β-d-glucoside
8 tenaxin 344 345.1 → 330.1
9 viscudulin III 6-O-β-d-glucoside 508 509.1 → 347.1
10 apigenin 270 271.1 → 153.1
11 apigetrin (apigenin-7-O-β-d-glucopuranoside) 432 433.1 → 271.1
12 * isocarthamidin-7-O-β-d-glucuronide 464 465.1 → 289.1
13 * carthamidin-7-O-β-d-glucuronide
14 scutellarin 462 463.1 → 287.1
15 chrysin-7-O-β-d-glucuronide 430 431.1 → 255.1
16 baicalein-7-O-β-d-glucoside 432 433.1 → 415.1
17 naringenin 272 273.1 → 153.1
18 oroxylin A 284 285.1 → 267.1
19 scullcapflavone II 374 375.1 → 345.1

* Structural isomers. In the hairy roots of S. baicalensis, 1–16 were found; S. pycnoclada, 1–16; S. przewalskii, 1–5, 7–14, 16–19; S. lateriflora, 1–7, 9–16, 18.