Table 1.
Thermodynamic parameters for different strengths of the applied force. The ratio is defined in Equation (2). The effective ratio is given by . The extrapolated equilibrium melting temperature has been calculated based on Equation (1). The extrapolated equilibrium heat of fusion is given by kJ/mol, see Figure 7.
Force | |||||
---|---|---|---|---|---|
(pN) | (kJ/mol/Monomer) | (kJ/mol/Monomer) | (%) | (%) | K |
0.0 | 4.183 | 0.000 | 0.0 | 0.0 | 523.2 |
1.4 | 4.605 | 0.017 | 0.3 | 0.2 | 524.2 |
2.8 | 4.975 | 0.069 | 1.4 | 0.8 | 527.4 |
4.2 | 5.345 | 0.159 | 3.0 | 1.8 | 532.6 |
5.6 | 5.979 | 0.286 | 4.8 | 3.2 | 539.9 |
7.0 | 6.349 | 0.443 | 7.0 | 4.9 | 548.8 |
8.4 | 6.929 | 0.632 | 9.1 | 7.0 | 559.8 |