Table 1.
Quantum Dot Properties.
| Heterostructureb | PLmax (nm) | FWHM (nm) | ε400c (M−1 cm−1) | Radiusd (nm) | ΦCHCL3e (%) | ΦH2Oe (%) | BH2Of x103 | |
|---|---|---|---|---|---|---|---|---|
| D1 | CdxZn1-xSeyS1-y | 510 | 30 | 170,000 | 5.0 ± 0.6 | 30.2 ± 1.0 | 28.9 ± 0.3 | 49 |
| D2 | InP/7ZnS | 560 | 63 | 360,000 | 2.2 ± 0.3 | 11.7 ± 2.5 | 0.7 ± 0.3 | 3 |
| D3 | InP/4ZnSe/3ZnS | 555 | 61 | 940,000 | 2.0 ± 0.2 | 17.0 ± 1.3 | 4.2 ± 0.6 | 40 |
| D4 | InP/7ZnSe/3ZnS | 560 | 47 | 2,400,000 | 2.3 ± 0.3 | 16.1 ± 0.2 | 4.6 ± 0.2 | 110 |
| A1 | InP/3ZnSa | 650 | 69 | 1,100,000 | 1.7 ± 0.2 | 14.6 ± 0.7 | 1.4 ± 0.2 | 15 |
Used as the acceptor QD; all other samples were used as donors.
QD composition. The first QD is an alloyed structure that forms a CdSe/ZnS QD with an alloyed interface based on the differential reactivities of the precursor materials; remaining heterostructures formed through SILAR deposition of shells on pre-made cores. The numbers before the shell compositions indicate the number of rounds of SILAR deposition, not final yield of shelling reaction.
ε400 determined using published empirical equations correlating 1s peak position to cores size and ε1s to map ε to the entire QD absorption spectrum.
Sizing based on TEM images (n = 76–212).
Absolute quantum yield measurements taken with an integrating sphere.
QD brightness in water calculated by multiplying ε400 and ФH2O and rounding to the nearest thousand.