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. 2021 Jun 8;125(23):5124–5145. doi: 10.1021/acs.jpca.1c03168

Table 1. Summary of Experimental and Theoretical Studies Relevant to C2–C4 Alkenes + Ḣ.

year author reaction(s) T (K) p (kPa) method
2020 Nagaraja et al.32 pyrolysis of C2–C6 1-alkenes 900–1800 200 single-pulse shock tube (SPST)
2020 Chen et al.20 Ḣ + C3H6 1065–1306 100–200 Ḣ-ARAS/shock-tube CCSD(T)/CBS//CCSD/6-311++G(3df,2p)
2018 Wang et al.33 C4–C6 alkenes + Ḣ and ĊH3     G4 composite method
2015 Manion et al.19 Ḣ + C4H8-1 880–1120 145–245 single-pulse shock tube (SPST)
2013 Matsugi et al.16 photodissociation of Ċ2H5     direct trajectory calculations ωB97X-D/6-31+G(d,p)
2013 Miller et al.18 dissociation of propyl radicals and other reactions on Ċ3H7 potential   0–HPL CCSD(T)/cc-pVTZ MP2/6-311++G(d,p)
2012 Yang et al.15 decomposition of ethyl iodide/dissociation of Ċ2H5 radicals 1150–1870 7.3–16.4 diaphragm-less shock tube/laser schlieren (LS) densitometry
2011 Rosado-Reyes et al.28 Ḣ + C3H6 922–1200 150–340 single-pulse shock tube (SPST)
2004 Miller et al.17 Ḣ + C2H2 and C2H4 300–2000 >0.13/HPL variational transition state theory (VTST), 2D master equation
1993 Hanning-Lee et al.8 Ḣ + C2H4 800 12.9–80.0 exciplex laser flash photolysis/time-resolved resonance fluorescence
1993 Feng et al.7 unimolecular decomposition of Ċ2H5 876–1094 0.1–1.9 heated tubular reactor/to a photoionization mass spectrometer
1993 Seakins et al.23 3H7 decomposition 720–910   laser flash photolysis/photoionization mass spectrometry
1992 Tsang36 database for hydrocarbon pyrolysis     estimate
1992 Hidaka et al.29 thermal decomposition of C3H6 1200–1800   laser kinetic absorption spectroscopy/GC
1991 Tsang37 database for hydrocarbon pyrolysis     estimate
1989 Löser et al.30 Ḣ atom abstraction by allyl radicals from hydrocarbons     BSBL
1987 Lightfoot et al.10 Ḣ + C2H4 285–604 6.7–80.0 laser flash photolysis/resonance fluorescence
1986 Munk et al.25 3H7 and iĊ3H7O2 298 101 UV absorption/pulse photolysis
1984 Pacey et al.13 pyrolysis of C2H6 902 HPL flow system
1982 Watanabe et al.27 Ḣ + C3H6 200–500   pulse radiolysis-resonance absorption
1982 Harris et al.31 Ḣ + C3H6/C4H8 298–455   flash photolysis-resonance fluorescence
1981 Sugawara et al.14 Ḣ- and D-atom addition to C2H4, C2H3D, C2D4, C2H2, and C2D2 206–461   pulse radiolysis-resonance absorption
1978 Lee et al.9 Ḣ + C2H4 198–320 0.13 flash photolysis-resonance fluorescence (FP-RF) technique
1973 Michael et al.12 Ḣ + C2H4     Lyman α photometry
1972 Kerr et al.24 evaluated kinetic data on gas-phase addition reactions      
1971 Kurylo et al.26 Ḣ + C3H6 298   resonance fluorescence of Lyman α radiation
1970 Barker et al.6 Ḣ + C2H4     discharge flow system with Lyman-α photometry, time-resolved Lyman-α photometric system, and discharge flow system with time-of-flight mass spectrometry