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. 2021 May 7;70(5):001363. doi: 10.1099/jmm.0.001363

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© 2021 The Authors

This is an open-access article distributed under the terms of the Creative Commons Attribution NonCommercial License. This article was made open access via a Publish and Read agreement between the Microbiology Society and the corresponding author’s institution.

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Fig. 5. — Molecular structure of manganese-based antibacterial compounds. (31)–(35) Mn(I) tricarbonyl complexes with ketoconazole, miconazole and clotrimazole ligands. The general formula of the Mn(I) tricarbonyl compounds is [Mn(CO)₃(bpy^H,COOCH ₃)(azole)]PF₆ where azole=the antibiotic ligand and bpy=bipyridine. The red box highlights azole ligand. The blue box indicates 2,2’-bpy ligands. (36)–(39) Mn(II) and Cu(II) complexes containing 1,10-phenanthroline and dicarboxylate ligands. (36) and (38) use Mn(II), (37) and (39) are the Cu(II) counterparts, respectively. (36) [Mn₂(oda)(phen₄)(H₂O)₂][Mn₂(oda)(phen)₄(oda₂]·4H₂O, (37) [Cu₂(oda)(phen)₄](ClO₄)₂·2.76H₂O·EtOH, (38) [(Mn(3,6,9-tdda)(phen)₂)·3H₂O·EtOH]n, (39) [(Cu(3,6,9-tdda)(phen)₂)·3H₂O·EtOH]_n. Figure adapted from the literature [177, 178].