Table 2. Summary of the Experimental Conditions and Rate Coefficients Obtained in This Work for the Gas-Phase Reaction of d₉-Butanol with OH Radicals.

reference: toluene. k(toluene+OH) = 1.8 × 10–12 exp(340/T) cm3 molecule–1 s–1, IUPAC recommended over 210–350 K
T (K)	[D9B]0a	[toluene]0a	[H2O2]0a	b	b	b	kD9B/ktoluene all ionsc	k1 (10–12)c cm3 molecule–1 s–1
263	2.95	2.46	95.9	0.69 ± 0.01	0.69 ± 0.01	0.64 ± 0.01	0.67 ± 0.03	4.39 ± 0.13
273	2.95	2.71	68.9	0.67 ± 0.01	0.62 ± 0.01	0.63 ± 0.01	0.64 ± 0.03	4.00 ± 0.12
293	5.41	4.67	54.1	0.65 ± 0.01	0.62 ± 0.01	0.57 ± 0.01	0.61 ± 0.04	3.50 ± 0.14
293	6.15	4.67	54.1	0.64 ± 0.01	0.62 ± 0.01	0.57 ± 0.01	0.61 ± 0.04
313	5.66	4.92	56.6	0.69 ± 0.01	0.62 ± 0.01	0.56 ± 0.01	0.62 ± 0.06	3.30 ± 0.20
333	5.90	5.41	61.5	0.75 ± 0.01	0.64 ± 0.01	0.68 ± 0.01	0.69 ± 0.06	3.45 ± 0.21
353	3.94	3.44	88.6	0.94 ± 0.01	0.89 ± 0.01	0.76 ± 0.01	0.86 ± 0.10	4.06 ± 0.36

reference: propanol. k(propanol+OH) = 4.6 × 10–12 exp(70/T) cm3 molecule–1 s–1, IUPAC recommended over260–380 K
T (K)	[D9B]0a	[Propanol]0a	[H2O2]0a	b	b	b	kD9B/kpropanol all ionsc	k1 (10–12)c cm3 molecule–1 s–1
263	4.67	5.90	192	0.79 ± 0.01	0.74 ± 0.01	Not usedd	0.76 ± 0.01	4.58 ± 0.29
263	2.95	3.44	477	0.79 ± 0.01	0.79 ± 0.01		0.79 ± 0.01	4.73 ± 0.05
273	4.92	6.15	98.4	0.68 ± 0.01	0.66 ± 0.01		0.67 ± 0.01	3.95 ± 0.06
293	5.41	6.64	106	0.60 ± 0.01	0.55 ± 0.01		0.58 ± 0.04	3.36 ± 0.23
313	5.66	7.13	113	0.60 ± 0.01	0.55 ± 0.01		0.58 ± 0.04	3.30 ± 0.23
333	5.90	7.38	120	0.62 ± 0.01	0.58 ± 0.01		0.60 ± 0.03	3.40 ± 0.17
353	6.40	7.87	128	0.66 ± 0.01	0.61 ± 0.01		0.64 ± 0.04	3.60 ± 0.22

reference: 1-butanol. k(1-butanol+OH) = 5.3 × 10–12 exp(140/T) cm3 molecule–1 s–1, IUPAC recommended over 260–380 K
T (K)	[D9B]0a	[1-butanol]0a	[H2O2]0a	b	b	b	kD9/kbutanolall ionsc	k1 (10–12)c cm3 molecule–1 s–1
263	4.67	4.92	479.7	0.51 ± 0.01	0.50 ± 0.01	0.52 ± 0.01	0.51 ± 0.01	4.60 ± 0.18
263	1.97	1.97	479.7	0.46 ± 0.01	0.48 ± 0.01	0.47 ± 0.01	0.47 ± 0.01	4.24 ± 0.08
273	4.92	4.92	496.9	0.39 ± 0.01	0.38 ± 0.01	0.40 ± 0.01	0.39 ± 0.01	3.45 ± 0.10
293	5.41	5.41	216.5	0.37 ± 0.01	0.34 ± 0.01	0.35 ± 0.01	0.35 ± 0.02	2.98 ± 0.23
333	5.90	6.15	120.5	0.40 ± 0.01	0.39 ± 0.01	0.38 ± 0.01	0.39 ± 0.01	3.15 ± 0.17
353	6.40	6.40	127.9	0.45 ± 0.01	0.44 ± 0.01	0.41 ± 0.01	0.43 ± 0.02	3.39 ± 0.22

reference: ethanol. k(ethanol+OH) = 6.7 × 10–18 T2 exp(511/T) cm3 molecule–1 s–1, IUPAC recommended over 216–599 K
				b			b		b
T (K)	[D9B]0a	[ethanol]0a	[H2O2]0a	102/47	81/47	66/47	99/45	81/45	64/45	kD9/kethanol all ionse	k1 (10–12)e cm3 molecule–1 s–1
293f	5.29	8.46	54.1	1.10 ± 0.01	1.07 ± 0.01	1.13 ± 0.02	1.00 ± 0.01	0.92 ± 0.01	0.95 ± 0.01	1.04 ± 0.10	3.43 ± 0.33
293f	5.29	8.46	103	1.00 ± 0.01	1.00 ± 0.01	1.10 ± 0.02	1.00 ± 0.01	1.08 ± 0.01	0.99 ± 0.01	1.06 ± 0.10	3.49 ± 0.33
293f	5.29	8.46	54	1.03 ± 0.01	0.97 ± 0.01	0.96 ± 0.01	1.13 ± 0.01	1.03 ± 0.01	1.06 ± 0.01	1.03 ± 0.06	3.39 ± 0.20
313f	5.66	9.05	113	1.08 ± 0.01	1.02 ± 0.01	1.10 ± 0.01	1.00 ± 0.01	0.96 ± 0.01	1.00 ± 0.01	1.03 ± 0.07	3.46 ± 0.24
333f	5.66	9.05	221	1.19 ± 0.01	1.16 ± 0.01	1.10 ± 0.01	1.07 ± 0.01	1.02 ± 0.01	1.06 ± 0.01	1.10 ± 0.06	3.79 ± 0.21

^aUnits of 10¹³ molecule cm^–3.

^bThe errors represent the 2σ fit precision (standard deviation).

^cThe quoted uncertainty is the 2σ standard error of the mean values.

^dIon relative ratios not used due to mass peak contribution.

^eThe mean values of the relative ratios for each precursor ion were averaged. The quoted uncertainty is the 2σ standard error of the mean values.

^fExperiment carried out at 50% RH.