Table 3. Summary of the Absolute Measurements of k₁^a.

T (K)	number of kinetic runs	[D9B] (1013molecule cm–3)	k1 (10–12) cm3 molecule–1 s–1
298b	9	0.80–10.1	3.60 ± 0.41
335b	11	0.55–9.68	3.40 ± 0.39
425c	9	0.49–8.78	4.11 ± 0.47
500c	9	0.13–11.1	4.70 ± 0.54
595c	8	0.67–11.2	5.79 ± 1.32d
670c	11	0.14–5.14	8.12 ± 1.85d
750c	7	0.32–4.36	9.80 ± 2.23d

^aThe total pressure in the reactor was 2 Torr, with the linear flow velocity in the reactor between 1980 and 2100 cm s^–1 and OH radical concentrations in the range of (2–3) × 10¹¹ molecule cm^–3. The combined uncertainty on k₁ was estimated to be about 11% by adding in quadrature the statistical error (≤4%) and that on the measurements of the absolute concentration of D9B (∼10%), flows (3%), pressure (2%), and temperature (1%).

^bHalocarbon wax-coated reactor.

^cUncoated quartz reactor.

^dThe error includes the systematic uncertainty and 20% conservative error to include OH regeneration of high-temperature studies.