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. 2021 May 24;143(21):7909–7914. doi: 10.1021/jacs.1c03459

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© 2021 The Authors. Published by American Chemical Society

Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).

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Scheme 1 — (a) Conceptual representation of various strategies for undirected C–H alkylation of arenes. (b) Experimental results for palladium-catalyzed aryl C–H alkylation via bromination versus thianthrenation. Two-step yield given for compounds 1 and 2. ^aProduct not detected by LCMS, GCMS, ¹H NMR spectroscopy, and ¹³C NMR spectroscopy (see the Supporting Information for details).