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Deglucosylation and subsequent spontaneous rearrangement of glucosinolates into various volatile natural products. Compiled from data in [4,13]. Abbreviations: ESM—epithiospecifier modifier protein; ESP—epithionitrile specifier protein; Glc—glucose; NSP—nitrile specifier protein; PEN2—atypical myrosinase; TGG—beta-thioglucoside glucohydrolase (myrosinase); TFP—thiocyanate-forming protein.
