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. 2021 Jul 7;22(14):7317. doi: 10.3390/ijms22147317
C concentration of polymer in the solution
Cn Flory’s characteristic ratio
E Horseradish Peroxidase (HRP)
g network correction factor
G relaxation modulus (Pa)
G storage modulus (Pa)
Ge equilibrium shear modulus treated by rubberlike elasticity theory (Pa)
Gx,m,a,c largest polymer chain with x monomeric units, m residual phenol groups, a activated phenol groups and c crosslinks
k Boltzmann’s constant (J/K)
kj kinetic rate constant of “j” reaction
kj,MC stochastic kinetic rate constant of “j” reaction
Mc number average molecular weight between two crosslinks
Mi molecular weight of the “ith” polymer chain
Mn,sol number average molecular weight in the solution (g/mol)
Mw weight average molecular weight in the system (g/mol)
MWm molecular weight of a repeating structural unit
Mw,sol weight average molecular weight in the solution (g/mol)
NA Avogadro’s Number
NCLD number chain length distribution
NE the number of enzyme species E
NH2O2 total number of hydrogen peroxide species
NR total number of polymer chains
Np number of primary molecules before crosslinking
NRE total number of reactions
rand1 randomly generated number uniformly distributed in the range of [0, 1]
rand2 randomly generated number uniformly distributed in the range of [0, 1]
rE2 mean square end-to-end distance of a strand
r02¯ mean square end-to-end distance of a non-constrained strand
Pi probability of reaction “i
R the universal gas constant (J∙mol−1K−1)
Rj the rate of the “j” chemical reaction
T absolute temperature (K)
u2,r polymer volume fraction at the relaxed state
u2,s polymer volume fraction at the equilibrium swollen state
V volume of the mixture
V 1 molar volume of the solvent
wg gel mass fraction
xi degree of polymerization of the “ith” polymer chain
Xc total number of possible combinations of reactive species in a reaction
Greek Symbols
Δt the time step between two reactions
ν number of network chains or segments per unit volume (m−3)
vc the number of moles of crosslinks per unit volume (mol∙m−3)
ve number effective network chains or segments per unit volume (m−3)
vo number of crosslinks per unit volume (m−3)
λ backbone bond factor
ξ mesh size of the network
ρ polymer density (kg∙m−3)
χ 1 Flory interaction parameter of the polymer-solvent