Table 2.
Migration levels of PFAS found in foods or food simulants.
| Country | Compound | Type of Samples | Origin of Samples | Method of Determination |
Food/Food Simulant | Results | Reference |
|---|---|---|---|---|---|---|---|
| Korea | PFPeA PFBS PFHxA PFHpA PFHxS PFOA PFNA PFOS PFDA PFUnDA PFDS PFDoDA PFTrDA PFTeDA PFHxDA PFODA |
Frying pans, baking utensils grills, baking paper | Large and local markets | LC-MS/MS | N-heptane, 50% ethanol, water and 4% acetic | PFODA: 3.05 μg L−1 in n-heptane PFNA: 2.12 μg/L in 50% ethanol | [30] |
| Spain | PFBA PFPeA L-PFBS PFHxA PFHpA L-PFHxS PFOA L-PFHpS PFNA L-PFOS PFDA PFUnDA L-PFDS PFDoDA PFTrDA PFTeDA |
Paper bags | Local markets | UPLC-MS/MS | Tenax® Whole milk and low-fat milk |
Increased migration in whole milk. Migration to Tenax® was 8% at 80 °C, 10% at 120 °C and 25% at 160 °C |
[31] |
| EEUU | PFOA Flurotelomers |
Popcorn bags | Not specified | LC/MS LC-MS/MS |
Popcorn oil, Myglyol | Migration levels of fluortelomers of 1.4 mg kg−1 before and 2.1 mg kg−1 after heating | [37] |
| EEUU | PFOS | Non-stick paper | EEUU retail markets | LC/MS | Ethanol/water (10, 20, 25 and 30% ethanol) | Increased migration in emulsified foods | [42] |
| Germany | FTOH | Paper Muffins | Not specified | GC/CI-MS | Tenax Muffins |
The higher the humidity the higher the FTOH migration | [43] |
| Egypt | PFOS PFOA |
Tefal kitchen utensils | Not specified | LC-MS | Fresh tomatoes as acidic foods White beans as a staple food |
Increased migration in acidic foods Increased migration in salted foods. Increased migration as the number of exhibitions increases. |
[44] |
| China | 6:2 FTOH 8:2 FTOH 10:2 FTOH 12:2 FTOH 14:2 FTOH 16:2 FTOH PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnDA PFDoDA PFTeDA PFPeDA PFHxDA PFHpDA PFODA |
Popcorn bags, materials labelled as ecological, cupcake packaging, etc. | Beijing retail markets and online | UPLC-MS/MS UPLC-QTOF-MS |
Water, 10%, 30% and 50% ethanol | Higher migration when the fluorine chain is smaller. Sum of 15 PFCA 0.006 μg cm−2 and 0.3 μg cm−2 for 7 FTOH |
[28] |
| Denmark | PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnDA PFDoDA PFTeA PFTrA 6.2 FTOH 8.2 FTOH 10.2 FTOH |
Dishes, Cupcake packaging |
Distributors and retailers in Norway | LC-MS/MS | 50% ethanol: water | Increased migration with increasing temperature | [29] |