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Kinetic analysis of cross-vinylsilane/diene-[4+2]-cycloaddition. (A.) Rate profiles for trials conducted with a ‘same excess’ of diene (dark open markers vs. light filled markers) but a different initial concentration. (B.) Rate dependence on diene 13j concentration. (C.) Rate dependence on vinylsilane 6b. (D.) Rate dependence on [Fe]tot. See supporting information for details.
