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. Author manuscript; available in PMC: 2021 Aug 4.
Published in final edited form as: ACS Catal. 2021 Apr 5;11(8):4670–4681. doi: 10.1021/acscatal.0c05656

Table 1:

Cis-indole isonitrile derivatives generated in this study, and isolated % yield of the desired Z-isomer.

graphic file with name nihms-1687527-t0002.jpg
Compound Substituent % Yield of Z-isomer
6 R1=OBzn,R2=H,X=C,Y=NC 11
7 R1=CN,R2=H,X=C,Y=NC 22
8 R1=OMe,R2=H,X=C,Y=NC 16
9 R1=H,R2=OMe,X=C,Y=NC 5
10 R1=Cl,R2=H,X=C,Y=NC 11
11 R1=H,R2=Cl,X=C,Y=NC 16
12 R1=F,R2=H,X=C,Y=NC 18
13 R1=H,R2=F,X=C,Y=NC 23
14 R1=Br,R2=H,X=C,Y=NC 18
15 R1=H,R2=Br,X=C,Y=NC 23
16 R1=I,R2=H,X=C,Y=NC 18
17 R1=H,R2=H,X=N,Y=NC 13
18 R1=F,R2=H,X=N,Y=NC 18
19 R1=H,R2=H,X=C,Y=CN 16