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. Author manuscript; available in PMC: 2022 Aug 10.
Published in final edited form as: Angew Chem Int Ed Engl. 2021 Jul 14;60(33):17925–17931. doi: 10.1002/anie.202105354

Figure 2.

Figure 2.

(A) Radical coupling accessibility model for aliphatic acyl azoliums with spin density distributions of optimized aliphatic acyl azolium structures (R = CH2Ph). (B) Proposed mechanism for the combined NHC/photoredox-catalyzed construction of aliphatic and α-amino ketones. Reported energies are for Az-B in kcal/mol.