Table 5.
[TAIm]OH ionic liquid catalyzed transesterification reaction[a]
|
| |||||
|---|---|---|---|---|---|
|
Entry |
R1 |
R2 |
Product |
Time [h] |
Conversion [%][b] |
|
1 |
Et |
Me |
10 a |
14 |
75 |
|
2 |
n‐Pr |
Me |
10 b |
9 |
80 |
|
3 |
n‐Bu |
Me |
10 c |
5 |
98 |
|
4 |
Me |
EtOH |
10 d |
10 |
80 |
|
5 |
n‐Pr |
EtOH |
10 e |
12 |
84 |
|
6 |
n‐Bu |
EtOH |
10 f |
12 |
85 |
|
7 |
Me |
n‐Pr |
10 g |
7 |
77 |
|
8 |
Et |
n‐Pr |
10 h |
5 |
95 |
|
9 |
n‐Bu |
n‐Pr |
10 i |
4 |
96 |
[a] Reaction conditions: Benzoate ester (5.0 mmol), alcohol (10 mmol), ionic liquid (1.0 ml, 10.0 mmol OH group), sealed tube. The all reactions were performed under boiling points of alcohols. [b] GC analysis.