| Cu1—N1 | 2.0208 (16) | C12—H12B | 0.9800 |
| Cu1—N2 | 2.0348 (17) | C12—H12C | 0.9800 |
| Cu1—N3 | 2.0123 (17) | C13—C14 | 1.392 (3) |
| Cu1—N4 | 2.0616 (18) | C13—C23 | 1.490 (3) |
| N1—C1 | 1.346 (3) | C14—H14 | 0.9500 |
| N1—C5 | 1.354 (2) | C14—C15 | 1.379 (4) |
| C1—C2 | 1.390 (3) | C15—H15 | 0.9500 |
| C1—C11 | 1.502 (3) | C15—C16 | 1.379 (4) |
| N2—C6 | 1.355 (2) | C16—H16 | 0.9500 |
| N2—C10 | 1.346 (3) | C16—C17 | 1.392 (3) |
| C2—H2 | 0.9500 | C17—C18 | 1.481 (3) |
| C2—C3 | 1.380 (3) | C18—C19 | 1.390 (3) |
| N3—C13 | 1.344 (3) | C19—H19 | 0.9500 |
| N3—C17 | 1.356 (3) | C19—C20 | 1.379 (4) |
| C3—H3 | 0.9500 | C20—H20 | 0.9500 |
| C3—C4 | 1.385 (3) | C20—C21 | 1.377 (4) |
| N4—C18 | 1.355 (3) | C21—H21 | 0.9500 |
| N4—C22 | 1.347 (3) | C21—C22 | 1.388 (3) |
| C4—H4 | 0.9500 | C22—C24 | 1.500 (3) |
| C4—C5 | 1.388 (3) | C23—H23A | 0.9800 |
| C5—C6 | 1.485 (3) | C23—H23B | 0.9800 |
| C6—C7 | 1.391 (3) | C23—H23C | 0.9800 |
| C7—H7 | 0.9500 | C24—H24A | 0.9800 |
| C7—C8 | 1.384 (3) | C24—H24B | 0.9800 |
| C8—H8 | 0.9500 | C24—H24C | 0.9800 |
| C8—C9 | 1.378 (3) | Zr1—F1 | 2.0113 (15) |
| C9—H9 | 0.9500 | Zr1—F1i | 2.0113 (15) |
| C9—C10 | 1.396 (3) | Zr1—F2i | 2.0183 (12) |
| C10—C12 | 1.503 (3) | Zr1—F2 | 2.0183 (12) |
| C11—H11A | 0.9800 | Zr1—F3 | 1.9955 (13) |
| C11—H11B | 0.9800 | Zr1—F3i | 1.9955 (13) |
| C11—H11C | 0.9800 | O1—H1A | 0.8699 |
| C12—H12A | 0.9800 | O1—H1B | 0.8703 |
| N1—Cu1—N2 | 81.40 (7) | H12B—C12—H12C | 109.5 |
| N1—Cu1—N4 | 116.24 (7) | N3—C13—C14 | 120.9 (2) |
| N2—Cu1—N4 | 120.45 (7) | N3—C13—C23 | 116.93 (18) |
| N3—Cu1—N1 | 136.29 (7) | C14—C13—C23 | 122.2 (2) |
| N3—Cu1—N2 | 126.16 (7) | C13—C14—H14 | 120.2 |
| N3—Cu1—N4 | 81.05 (7) | C15—C14—C13 | 119.6 (2) |
| C1—N1—Cu1 | 127.37 (14) | C15—C14—H14 | 120.2 |
| C1—N1—C5 | 119.06 (17) | C14—C15—H15 | 120.2 |
| C5—N1—Cu1 | 112.61 (13) | C14—C15—C16 | 119.7 (2) |
| N1—C1—C2 | 121.76 (18) | C16—C15—H15 | 120.2 |
| N1—C1—C11 | 116.67 (19) | C15—C16—H16 | 120.7 |
| C2—C1—C11 | 121.55 (19) | C15—C16—C17 | 118.7 (2) |
| C6—N2—Cu1 | 112.50 (13) | C17—C16—H16 | 120.7 |
| C10—N2—Cu1 | 128.32 (14) | N3—C17—C16 | 121.5 (2) |
| C10—N2—C6 | 119.07 (17) | N3—C17—C18 | 115.35 (18) |
| C1—C2—H2 | 120.5 | C16—C17—C18 | 123.1 (2) |
| C3—C2—C1 | 119.10 (19) | N4—C18—C17 | 115.47 (18) |
| C3—C2—H2 | 120.5 | N4—C18—C19 | 121.7 (2) |
| C13—N3—Cu1 | 125.56 (14) | C19—C18—C17 | 122.8 (2) |
| C13—N3—C17 | 119.66 (18) | C18—C19—H19 | 120.6 |
| C17—N3—Cu1 | 114.36 (14) | C20—C19—C18 | 118.8 (2) |
| C2—C3—H3 | 120.3 | C20—C19—H19 | 120.6 |
| C2—C3—C4 | 119.43 (19) | C19—C20—H20 | 120.3 |
| C4—C3—H3 | 120.3 | C21—C20—C19 | 119.4 (2) |
| C18—N4—Cu1 | 113.01 (14) | C21—C20—H20 | 120.3 |
| C22—N4—Cu1 | 127.62 (15) | C20—C21—H21 | 120.0 |
| C22—N4—C18 | 119.34 (19) | C20—C21—C22 | 119.9 (2) |
| C3—C4—H4 | 120.5 | C22—C21—H21 | 120.0 |
| C3—C4—C5 | 118.94 (18) | N4—C22—C21 | 120.8 (2) |
| C5—C4—H4 | 120.5 | N4—C22—C24 | 116.8 (2) |
| N1—C5—C4 | 121.67 (18) | C21—C22—C24 | 122.3 (2) |
| N1—C5—C6 | 115.42 (17) | C13—C23—H23A | 109.5 |
| C4—C5—C6 | 122.90 (17) | C13—C23—H23B | 109.5 |
| N2—C6—C5 | 115.28 (16) | C13—C23—H23C | 109.5 |
| N2—C6—C7 | 121.72 (18) | H23A—C23—H23B | 109.5 |
| C7—C6—C5 | 122.97 (18) | H23A—C23—H23C | 109.5 |
| C6—C7—H7 | 120.6 | H23B—C23—H23C | 109.5 |
| C8—C7—C6 | 118.70 (19) | C22—C24—H24A | 109.5 |
| C8—C7—H7 | 120.6 | C22—C24—H24B | 109.5 |
| C7—C8—H8 | 120.1 | C22—C24—H24C | 109.5 |
| C9—C8—C7 | 119.71 (19) | H24A—C24—H24B | 109.5 |
| C9—C8—H8 | 120.1 | H24A—C24—H24C | 109.5 |
| C8—C9—H9 | 120.5 | H24B—C24—H24C | 109.5 |
| C8—C9—C10 | 119.0 (2) | F1i—Zr1—F1 | 180.00 (9) |
| C10—C9—H9 | 120.5 | F1—Zr1—F2i | 89.69 (6) |
| N2—C10—C9 | 121.56 (19) | F1—Zr1—F2 | 90.31 (6) |
| N2—C10—C12 | 116.3 (2) | F1i—Zr1—F2 | 89.69 (6) |
| C9—C10—C12 | 122.1 (2) | F1i—Zr1—F2i | 90.31 (6) |
| C1—C11—H11A | 109.5 | F2—Zr1—F2i | 180.0 |
| C1—C11—H11B | 109.5 | F3i—Zr1—F1 | 89.90 (6) |
| C1—C11—H11C | 109.5 | F3—Zr1—F1i | 89.90 (6) |
| H11A—C11—H11B | 109.5 | F3—Zr1—F1 | 90.10 (6) |
| H11A—C11—H11C | 109.5 | F3i—Zr1—F1i | 90.10 (6) |
| H11B—C11—H11C | 109.5 | F3i—Zr1—F2i | 89.43 (5) |
| C10—C12—H12A | 109.5 | F3—Zr1—F2 | 89.43 (5) |
| C10—C12—H12B | 109.5 | F3—Zr1—F2i | 90.57 (5) |
| C10—C12—H12C | 109.5 | F3i—Zr1—F2 | 90.57 (5) |
| H12A—C12—H12B | 109.5 | F3i—Zr1—F3 | 180.0 |
| H12A—C12—H12C | 109.5 | H1A—O1—H1B | 109.5 |
| Cu1—N1—C1—C2 | 166.88 (15) | C5—N1—C1—C2 | −1.0 (3) |
| Cu1—N1—C1—C11 | −14.7 (3) | C5—N1—C1—C11 | 177.37 (19) |
| Cu1—N1—C5—C4 | −167.35 (15) | C5—C6—C7—C8 | −173.85 (19) |
| Cu1—N1—C5—C6 | 14.0 (2) | C6—N2—C10—C9 | 0.5 (3) |
| Cu1—N2—C6—C5 | −9.8 (2) | C6—N2—C10—C12 | 179.4 (2) |
| Cu1—N2—C6—C7 | 172.18 (15) | C6—C7—C8—C9 | 0.2 (3) |
| Cu1—N2—C10—C9 | −175.40 (16) | C7—C8—C9—C10 | −3.8 (3) |
| Cu1—N2—C10—C12 | 3.4 (3) | C8—C9—C10—N2 | 3.6 (3) |
| Cu1—N3—C13—C14 | 170.26 (16) | C8—C9—C10—C12 | −175.2 (2) |
| Cu1—N3—C13—C23 | −10.0 (3) | C10—N2—C6—C5 | 173.65 (18) |
| Cu1—N3—C17—C16 | −171.70 (16) | C10—N2—C6—C7 | −4.4 (3) |
| Cu1—N3—C17—C18 | 9.7 (2) | C11—C1—C2—C3 | −179.0 (2) |
| Cu1—N4—C18—C17 | −0.4 (2) | C13—N3—C17—C16 | 1.3 (3) |
| Cu1—N4—C18—C19 | −179.26 (16) | C13—N3—C17—C18 | −177.34 (18) |
| Cu1—N4—C22—C21 | 177.41 (16) | C13—C14—C15—C16 | 1.1 (4) |
| Cu1—N4—C22—C24 | −1.9 (3) | C14—C15—C16—C17 | −1.7 (3) |
| N1—C1—C2—C3 | −0.7 (3) | C15—C16—C17—N3 | 0.5 (3) |
| N1—C5—C6—N2 | −2.7 (3) | C15—C16—C17—C18 | 179.0 (2) |
| N1—C5—C6—C7 | 175.24 (18) | C16—C17—C18—N4 | 175.31 (19) |
| C1—N1—C5—C4 | 2.3 (3) | C16—C17—C18—C19 | −5.9 (3) |
| C1—N1—C5—C6 | −176.43 (18) | C17—N3—C13—C14 | −1.9 (3) |
| C1—C2—C3—C4 | 1.2 (3) | C17—N3—C13—C23 | 177.87 (19) |
| N2—C6—C7—C8 | 4.0 (3) | C17—C18—C19—C20 | −177.4 (2) |
| C2—C3—C4—C5 | 0.0 (3) | C18—N4—C22—C21 | −0.7 (3) |
| N3—C13—C14—C15 | 0.7 (3) | C18—N4—C22—C24 | 179.95 (19) |
| N3—C17—C18—N4 | −6.1 (3) | C18—C19—C20—C21 | −0.2 (3) |
| N3—C17—C18—C19 | 172.72 (19) | C19—C20—C21—C22 | −1.4 (4) |
| C3—C4—C5—N1 | −1.7 (3) | C20—C21—C22—N4 | 1.8 (3) |
| C3—C4—C5—C6 | 176.86 (19) | C20—C21—C22—C24 | −178.8 (2) |
| N4—C18—C19—C20 | 1.3 (3) | C22—N4—C18—C17 | 177.93 (18) |
| C4—C5—C6—N2 | 178.58 (18) | C22—N4—C18—C19 | −0.9 (3) |
| C4—C5—C6—C7 | −3.4 (3) | C23—C13—C14—C15 | −179.0 (2) |