| Crystal data |
| Chemical formula |
[DyCl2(C19H15BN)(C4H8O)4] |
[YCl2(C19H15BN)(C4H8O)4] |
C8H20N+·C24H20B3O3
−
|
C8H20N+·C25H20B2NO−
|
2C18H36KN2O6
+·C24H20B3O3
−·C14H13BN−·2C4H8O |
|
M
r
|
789.94 |
716.35 |
519.08 |
502.29 |
1570.27 |
| Crystal system, space group |
Triclinic, P\overline{1} |
Triclinic, P\overline{1} |
Monoclinic, P21/n
|
Monoclinic, P21/n
|
Orthorhombic, P
c
a21
|
| Temperature (K) |
158 |
173 |
133 |
88 |
88 |
|
a, b, c (Å) |
12.0043 (17), 12.5261 (17), 13.4913 (19) |
12.0404 (9), 12.5428 (9), 13.4654 (10) |
9.7245 (7), 18.3021 (13), 16.7716 (12) |
11.0269 (8), 13.9387 (11), 18.8488 (14) |
27.193 (2), 14.5520 (11), 21.2218 (16) |
| α, β, γ (°) |
114.7161 (13), 101.2230 (16), 94.2256 (16) |
114.6967 (8), 101.3142 (9), 94.3882 (9) |
90, 101.5456 (9), 90 |
90, 100.6357 (10), 90 |
90, 90, 90 |
|
V (Å3) |
1780.0 (4) |
1782.7 (2) |
2924.6 (4) |
2847.3 (4) |
8397.7 (11) |
|
Z
|
2 |
2 |
4 |
4 |
4 |
| Radiation type |
Mo Kα |
Mo Kα |
Mo Kα |
Mo Kα |
Mo Kα |
| μ (mm−1) |
2.29 |
1.82 |
0.07 |
0.07 |
0.18 |
| Crystal size (mm) |
0.39 × 0.33 × 0.26 |
0.32 × 0.20 × 0.13 |
0.37 × 0.33 × 0.23 |
0.28 × 0.27 × 0.22 |
0.45 × 0.33 × 0.28 |
| |
| Data collection |
| Diffractometer |
Bruker SMART APEXII CCD |
Bruker SMART APEXII CCD |
Bruker SMART APEXII CCD |
Bruker SMART APEXII CCD |
Bruker SMART APEXII CCD |
| Absorption correction |
Numerical (SADABS; Krause et al., 2015 ▸) |
Multi-scan (TWINABS; Sheldrick, 2012 ▸) |
Multi-scan (SADABS; Krause et al., 2015 ▸) |
Multi-scan (SADABS; Krause et al., 2015 ▸) |
Multi-scan (SADABS; Krause et al., 2015 ▸) |
|
T
min, T
max
|
0.558, 0.696 |
0.576, 0.746 |
0.834, 0.862 |
0.715, 0.746 |
0.825, 0.862 |
| No. of measured, independent and observed [I > 2σ(I)] reflections |
21440, 8460, 7562 |
7988, 7988, 6188 |
31741, 5959, 5030 |
34768, 7242, 5500 |
85621, 15958, 14236 |
|
R
int
|
0.019 |
– |
0.029 |
0.042 |
0.038 |
| (sin θ/λ)max (Å−1) |
0.680 |
0.650 |
0.625 |
0.685 |
0.610 |
| |
| Refinement |
|
R[F
2 > 2σ(F
2)], wR(F
2), S
|
0.024, 0.061, 1.04 |
0.047, 0.102, 1.04 |
0.064, 0.179, 1.02 |
0.048, 0.119, 1.04 |
0.074, 0.209, 1.06 |
| No. of reflections |
8460 |
7988 |
5959 |
7242 |
15958 |
| No. of parameters |
406 |
425 |
442 |
347 |
988 |
| No. of restraints |
0 |
0 |
0 |
0 |
1 |
| H-atom treatment |
H-atom parameters constrained |
H-atom parameters constrained |
H-atom parameters constrained |
H-atom parameters constrained |
H-atom parameters constrained |
| Δρmax, Δρmin (e Å−3) |
1.34, −0.89 |
0.64, −0.81 |
1.06, −0.47 |
0.41, −0.24 |
0.78, −0.34 |
