Table 3. Experimental details.
| Crystal data | |
| Chemical formula | [Mn(NCS)2(C6H8N2S)2] |
| M r | 387.39 |
| Crystal system, space group | Monoclinic, P21/n |
| Temperature (K) | 200 |
| a, b, c (Å) | 8.2157 (3), 12.2356 (5), 8.9601 (3) |
| β (°) | 99.736 (3) |
| V (Å3) | 887.73 (6) |
| Z | 2 |
| Radiation type | Mo Kα |
| μ (mm−1) | 0.99 |
| Crystal size (mm) | 0.03 × 0.03 × 0.01 |
| Data collection | |
| Diffractometer | Stoe IPDS2 |
| Absorption correction | Numerical (X-SHAPE and X-RED 32; Stoe, 2002 ▸) |
| T min, T max | 0.856, 0.980 |
| No. of measured, independent and observed [I > 2σ(I)] reflections | 12559, 1939, 1755 |
| R int | 0.040 |
| (sin θ/λ)max (Å−1) | 0.639 |
| Refinement | |
| R[F 2 > 2σ(F 2)], wR(F 2), S | 0.031, 0.073, 1.14 |
| No. of reflections | 1939 |
| No. of parameters | 106 |
| H-atom treatment | H-atom parameters constrained |
| Δρmax, Δρmin (e Å−3) | 0.27, −0.22 |