Table 1.
Electrochemical sensors based on polythiophene (PTh), poly-(3,4-ethylenedioxythiophene) (PEDOT), polyaniline (PANI), and polypyrrole (PPy) currently reported in literature.
Electrochemical Device | Analyte | Working Media | Sample | Analytical Parameters | Ref. | |
---|---|---|---|---|---|---|
LD (µM) |
LR (µM) |
|||||
PTh | ||||||
MWCNT/PTh/Pt | BPA | PBS pH 7.5 | Water | 0.009 | 0.05–0.4 | [62] |
MnO2/PTh/rGO/GCE | MP | PBS pH 7 | Human urine and blood | 0.0057 | 0.5–10 | [63] |
GO-4-ATP-Au-PTh/Au GCE | Nicotine | PBS pH 7 | Serum, urine, cigarette | 0.17 | 1.0–30 | [64] |
PTh-AgBr | Glucose | NaOH | Human blood plasma | 0.31 | 4–5000 | [65] |
PTh-Ag/GCE | L-Tryp | PBS pH 7 | Soybeans extract | 0.020 | 0.2–400 | [66] |
PEDOT | ||||||
PEDOT/IL/GCE | DA | PBS pH 7.4 | Human urine | 0.033 | 0.2–328 | [67] |
UiO-66-NH2@PEDOT/GA/GCE | PCMC | ABS pH 6 | Tap water | 0.2 | 0.6–18 | [68] |
PEDOT/AG/GCE | AC | PBS pH 7 | Local tablets | 0.041 | 0.15–5881 | [69] |
Cu2O/PEDOT/MWCNT | Glucose | NaOH | Human blood serum | 0.04 | 0.495–374 | [70] |
GC/PEDOT-AuNPs-SV | CA | PBS pH 7 | Juice | 4.24 | 10–1000 | [71] |
PEDOT-Tyr/SNG-C | CA | PBS pH 7 | Wine, beer | 4.33 | 10–300 | [72] |
PEDOT/PEDOT-SH/Au | Nitrite | PBS pH 6.9 | Tap water, milk | 0.051 | 0.15–1000 | [73] |
PEDOT/Au | UA | PBS pH 6.6 | Milk | 7.0 | 6–200 | [74] |
GCE/PEDOT-MC/AgNPs | Rutin | PBS pH 3 | Tablets | 0.0035 | 0.005–0.5 | [75] |
Pt/PEDOT-PBNPS | H2O2 | ABS pH 5.5 | Human blood | 1.4 | 5–1000 | [76] |
PANI | ||||||
Co3O4@PANINFs/GCE | Glucose | PBS pH 7.4 | Human serum | 60 | 100–8000 | [77] |
TiO2@PANI@Au/GCE | Hydrazine | NH3/NH4+ pH 9 | Power plant sewage | 0.15 | 0.9–1200 | [78] |
PANI/SnO2/GCE | Nitrite | PBS pH 6 | - | 0.04 | 0.12–7777 | [79] |
GCE/PANI-Fe3O4 | DA | PBS pH 7 | Water | 0.176 | 0.2–2.4 | [80] |
GCE/PANI-NiO | DA | PBS pH 7 | Water | 0.166 | 0.2–2.4 | [80] |
α-Fe2O3/PANI/GCE | UA | PBS pH 7 | Human urine | 0.038 | 0.01–5 | [81] |
NiO-NPs@PANINS/SPE | Glucose | NaOH | Human blood serum | 0.06 | 1–3000 | [82] |
MeGO/PANI | AA | PBS pH 7.4 | - | 2.0 | 8–5000 | [83] |
PPy | ||||||
Fe3O4@PPy/MWCNTs/GE | AT | BR pH 4 | Serum, tablets | 0.0230 | 0.0314–201 | [84] |
AuNP/PPy/GCE | L-dopa | PBS pH 7 | Urine | 0.075 | 0.1–6.0 | [85] |
PDA/PPy/GCE | UA | PBS pH 8 | Human serum, urine | 0.11 | 0.5–40 | [86] |
PGE/CuO-NPs/PPy | TR | PBS pH 8.5 | Tablets | 0.001 | 0.005–380 | [87] |
PPy:LAC | Lactate | KNO3 | Human tear, rat blood | 81.0 | 100–10,000 | [88] |
AuCu/PPy/Cu-TCCP | H2O2 | PBS pH 8 | Medical H2O2 solution | 0.0067 | 0.71–24,100 | [89] |
AA: ascorbic acid; ABS: acetic buffer solution; AC: acetaminophen; AT: atorvastatin; ATP: adenosine triphosphate; BPA: bisphenol A; BR: Britton-Robinson; CA: caffeic acid; CuO-NPs: copper oxide nanoparticles; DA: dopamine; PTh: polythiophene; GA: graphene aerogel; GCE: glassy carbon electrode; IL: ionic liquid; LAC: lactate; LD: limit of detection; LR: linear range; L-Tryp: L-tryptophan; MC: mesoporous carbon; MP: methyl parathion; MWCNT: multi-walled carbon nanotubes; PANI: polyaniline; PANINS: polyaniline nanofibers; PBNPS: Prussian blue nanoparticles; PBS: phosphate buffer solution; PCMC: p-chloromethylcresol; PEDOT: poly-(3,4-ethylenedioxythiophene); PGE: pencil graphite electrode; PPy: polypyrrole; rGO: reduced-graphene oxide; SPE: screen-printed electrode; SV: sinusoidal voltage; TCCP: meso-tetra-(4-carboxyphenyl)-substituted porphyrins; TR: tramadol; and UA: uric acid.