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. 2021 Jul 22;21(15):4976. doi: 10.3390/s21154976

Table 1.

Electrochemical sensors based on polythiophene (PTh), poly-(3,4-ethylenedioxythiophene) (PEDOT), polyaniline (PANI), and polypyrrole (PPy) currently reported in literature.

Electrochemical Device Analyte Working Media Sample Analytical Parameters Ref.
LD
(µM)
LR
(µM)
PTh
MWCNT/PTh/Pt BPA PBS pH 7.5 Water 0.009 0.05–0.4 [62]
MnO2/PTh/rGO/GCE MP PBS pH 7 Human urine and blood 0.0057 0.5–10 [63]
GO-4-ATP-Au-PTh/Au GCE Nicotine PBS pH 7 Serum, urine, cigarette 0.17 1.0–30 [64]
PTh-AgBr Glucose NaOH Human blood plasma 0.31 4–5000 [65]
PTh-Ag/GCE L-Tryp PBS pH 7 Soybeans extract 0.020 0.2–400 [66]
PEDOT
PEDOT/IL/GCE DA PBS pH 7.4 Human urine 0.033 0.2–328 [67]
UiO-66-NH2@PEDOT/GA/GCE PCMC ABS pH 6 Tap water 0.2 0.6–18 [68]
PEDOT/AG/GCE AC PBS pH 7 Local tablets 0.041 0.15–5881 [69]
Cu2O/PEDOT/MWCNT Glucose NaOH Human blood serum 0.04 0.495–374 [70]
GC/PEDOT-AuNPs-SV CA PBS pH 7 Juice 4.24 10–1000 [71]
PEDOT-Tyr/SNG-C CA PBS pH 7 Wine, beer 4.33 10–300 [72]
PEDOT/PEDOT-SH/Au Nitrite PBS pH 6.9 Tap water, milk 0.051 0.15–1000 [73]
PEDOT/Au UA PBS pH 6.6 Milk 7.0 6–200 [74]
GCE/PEDOT-MC/AgNPs Rutin PBS pH 3 Tablets 0.0035 0.005–0.5 [75]
Pt/PEDOT-PBNPS H2O2 ABS pH 5.5 Human blood 1.4 5–1000 [76]
PANI
Co3O4@PANINFs/GCE Glucose PBS pH 7.4 Human serum 60 100–8000 [77]
TiO2@PANI@Au/GCE Hydrazine NH3/NH4+ pH 9 Power plant sewage 0.15 0.9–1200 [78]
PANI/SnO2/GCE Nitrite PBS pH 6 - 0.04 0.12–7777 [79]
GCE/PANI-Fe3O4 DA PBS pH 7 Water 0.176 0.2–2.4 [80]
GCE/PANI-NiO DA PBS pH 7 Water 0.166 0.2–2.4 [80]
α-Fe2O3/PANI/GCE UA PBS pH 7 Human urine 0.038 0.01–5 [81]
NiO-NPs@PANINS/SPE Glucose NaOH Human blood serum 0.06 1–3000 [82]
MeGO/PANI AA PBS pH 7.4 - 2.0 8–5000 [83]
PPy
Fe3O4@PPy/MWCNTs/GE AT BR pH 4 Serum, tablets 0.0230 0.0314–201 [84]
AuNP/PPy/GCE L-dopa PBS pH 7 Urine 0.075 0.1–6.0 [85]
PDA/PPy/GCE UA PBS pH 8 Human serum, urine 0.11 0.5–40 [86]
PGE/CuO-NPs/PPy TR PBS pH 8.5 Tablets 0.001 0.005–380 [87]
PPy:LAC Lactate KNO3 Human tear, rat blood 81.0 100–10,000 [88]
AuCu/PPy/Cu-TCCP H2O2 PBS pH 8 Medical H2O2 solution 0.0067 0.71–24,100 [89]

AA: ascorbic acid; ABS: acetic buffer solution; AC: acetaminophen; AT: atorvastatin; ATP: adenosine triphosphate; BPA: bisphenol A; BR: Britton-Robinson; CA: caffeic acid; CuO-NPs: copper oxide nanoparticles; DA: dopamine; PTh: polythiophene; GA: graphene aerogel; GCE: glassy carbon electrode; IL: ionic liquid; LAC: lactate; LD: limit of detection; LR: linear range; L-Tryp: L-tryptophan; MC: mesoporous carbon; MP: methyl parathion; MWCNT: multi-walled carbon nanotubes; PANI: polyaniline; PANINS: polyaniline nanofibers; PBNPS: Prussian blue nanoparticles; PBS: phosphate buffer solution; PCMC: p-chloromethylcresol; PEDOT: poly-(3,4-ethylenedioxythiophene); PGE: pencil graphite electrode; PPy: polypyrrole; rGO: reduced-graphene oxide; SPE: screen-printed electrode; SV: sinusoidal voltage; TCCP: meso-tetra-(4-carboxyphenyl)-substituted porphyrins; TR: tramadol; and UA: uric acid.