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. 2021 Aug 3;26(15):4694. doi: 10.3390/molecules26154694

Table 1.

Chemical composition (%) of the essential oils extracted from crude organic propolis and from its moist and dry residues.

Compound RIcalc RIlit EOP EOMR EODR
%
Hexanal 801 801 0.19 - -
Tricyclene 922 926 1.54 - -
α-Thujene 931 930 1.01 0.97 1.13
α-Pinene 938 939 66.48 42.17 16.25
Camphene 952 954 2.94 - 0.55
Thuja-2,4(10)-diene 958 960 2.04 5.02 4.67
Sabinene 977 975 0.45 - 0.50
β-Pinene 981 979 18.46 10.29 5.15
Myrcene 995 990 0.67 1.32 -
n-Octanal 1005 998 - 0.6 0.35
α-Terpinene 1020 1017 0.22 0.67 0.91
p-Cymene 1027 1024 0.81 2.29 2.07
Limonene 1032 1029 2.04 2.72 3.07
γ-Terpinene 1062 1059 0.26 0.71 0.99
Acetophenone 1068 1065 0.35 0.68 0.64
n-Nonanal 1105 1100 - 0.62 0.97
Ethyl benzoate 1172 1173 - 4.74 7.80
n-Decanal 1206 1201 - 0.52 1.32
α-Copaene 1377 1376 - 0.93 -
Ethyl decanoate 1395 1395 - - 0.74
(E)-Caryophyllene 1426 1419 - 1.18 3.02
Zonarene 1529 1529 - - 3.82
Total 97.46 75.43 53.95

RIcalc: Retention index calculated; RIlit: Retention index from the literature; EOP: essential oil of propolis; EOMR: essential oil from the moist residue of propolis; EODR: essential oil from the dry residue of propolis. The column used was RTX5MS (RESTREK).