Table 1.
Summary of di- and triblock copolymers characterizations.
| No. | Target Composition | Conversion% | Calculated DP * | Mean Diamater | Morphology | |
|---|---|---|---|---|---|---|
| DLS (nm) | TEM (nm) | |||||
| 1 | PDMA50 | 71 | 39 | |||
| 2 | PDMA39-PHFBMA50 | 99 | 50 | 27 (0.08) | 16 | Sphere |
| 3 | PDMA39-PHFBMA100 | 99 | 99 | 70 (0.04) | 31 | Sphere |
| 4 | PDMA39-PHFBMA150 | 99 | 149 | 89 (0.07) | 53 | Sphere |
| 5 | PDMA39-PHFBMA200 | 94 | 188 | 125 (0.08) | 65 | Sphere |
| 6 | PDMA39-PHFBMA300 | 99 | 299 | 184 (0.04) | 99 | Sphere |
| 7 | PDMA39-PHFBMA50-PBzMA70 | 99 | 69 | 60 (0.10) | 28 | Sphere |
| 8 | PDMA39-PHFBMA99-PBzMA70 | 99 | 69 | 70 (0.12) | 48 | Sphere |
| 9 | PDMA39-PHFBMA149-PBzMA70 | 99 | 69 | 80 (0.07) | 224 | Sphere |
| 10 | PDMA39-PHFBMA199-PBzMA70 | 94 | 66 | 375 (0.09) | 213 | Sphere |
| 11 | PDMA39-PHFBMA50-PBzMA200 | 99 | 198 | 400 (0.11) | 30 | Sphere |
| 12 | PDMA39-PHFBMA99-PBzMA200 | 99 | 198 | 1190 (0.13) | 43 | Sphere |
| 13 | PDMA39-PHFBMA149-PBzMA200 | 99 | 198 | 1247 (0.09) | 68 | Sphere |
| 14 | PDMA39-PHFBMA199-PBzMA200 | 99 | 198 | 1810 (0.10) | 99 | Sphere |
| 15 | PDMA39-PBzMA60 | 98 | 59 | 40 (0.05) | 26 | Sphere |
| 16 | PDMA39-PBzMA70 | 99 | 69 | 46 (0.02) | 30 | Sphere |
| 17 | PDMA39-PBzMA85 | 99 | 84 | 87 (0.07) | 60 | Sphere/Worm |
| 18 | PDMA39-PBzMA120 | 97 | 117 | 160 (0.07) | 86 | Worms/Vesicle |
| 19 | PDMA39-PBzMA200 | 99 | 198 | 325 (0.04) | 204 | Vesicle |
| 20 | PDMA39-PBzMA69-PHFBMA50 | 99 | 50 | 100 (0.12) | 48 | Sphere |
| 21 | PDMA39-PBzMA69-PHFBMA100 | 99 | 99 | 125 (0.08) | 93 | Sphere |
| 22 | PDMA39-PBzMA69-PHFBMA150 | 99 | 149 | 200 (0.011) | 120 | Sphere |
| 23 | PDMA39-PBzMA69-PHFBMA200 | 98 | 196 | 200 (0.14) | 336 | Sphere |
| 24 | PDMA39-PBzMA99-PHFBMA100 | 65 | 65 | 360 (0.07) | 150 | Vesicle |
| 25 | PDMA39-PBzMA149-PHFBMA150 | 94 | 141 | 860 (0.10) | 230 | Vesicle |
| 26 | PDMA39-PBzMA198-PHFBMA50 | 99 | 50 | 210 (0.06) | 73 | Sphere |
| 27 | PDMA39-PBzMA198-PHFBMA100 | 96 | 96 | 430 (0.14) | 122 | Fused Spheres |
| 28 | PDMA39-PBzMA198-PHFBMA150 | 96 | 144 | 600 (0.11) | 145 | Vesicle |
| 29 | PDMA39-PBzMA198-PHFBMA200 | 94 | 189 | 2200 (0.12) | 304 | Vesicle |
* Calculated DP = Target DP × Conversion by 1H NMR.