. 2021 Jul 23;26(15):4443. doi: 10.3390/molecules26154443

Table 2.

LC-MS results of non-polysaccharide constituents in GEP-1 hydrolysate.

Name	Molecular Formula	Theoric Mass	t_R (min)	m/z Experimental	pos/neg	Error (ppm)
CA	C₆H₈O₇	192.0265	2.72	193.0343	[M + H]⁺	−0.047
1HA	C₇H₈O₂	124.0519	1.12	107.0489	[M − H₂O + H]⁺	−2.535
2HA	C₁₄H₁₄O₃	230.0937	8.44	213.0913	[M − H₂O + H]⁺	1.473
3HA	C₂₁H₂₀O₄	336.1356	8.86	319.1326	[M − H₂O + H]⁺	-0.894
4HA	C₂₈H₂₆O₅	442.1775	9.16	425.1745	[M − H₂O + H]⁺	−0.554
5HA	C₃₅H₃₂O₆	548.2193	9.40	531.2161	[M − H₂O + H]⁺	−1.018
6HA	C₄₂H₃₈O₇	654.2612	9.52	637.2576	[M − H₂O + H]⁺	−1.311
7HA	C₄₉H₄₄O₈	760.3031	9.58	743.3001	[M − H₂O + H]⁺	−0.377
Glc	C₆H₁₂O₆	180.0628	1.02	163.0597	[M − H₂O + H]⁺	−2.207
CA	C₆H₈O₇	192.0265	2.75	191.0196	[M − H]⁻	5.293
Glc	C₆H₁₂O₆	180.0628	1.02	179.0561	[M − H]⁻	0.160
1HA	C₇H₈O₂	124.0519	1.12	105.0349	[M − H₂O + H]⁻	2.493
2HA	C₁₄H₁₄O₃	230.0937	8.44	211.0766	[M − H₂O − H]⁻	0.839
3HA	C₂₁H₂₀O₄	336.1356	8.92	317.1182	[M − H₂O − H]⁻	−0.403
4HA	C₂₈H₂₆O₅	442.1775	9.16	423.1605	[M − H₂O − H]⁻	0.656
4HA	C₂₈H₂₆O₅	442.1775	9.16	411.1606	[M − CH₂O − H]⁻	1.113
5HA	C₃₅H₃₂O₆	548.2193	9.13	529.2029	[M − H₂O − H]⁻	1.681
6HA	C₄₂H₃₈O₇	654.2612	9.38	635.2458	[M − H₂O − H]⁻	2.956
7HA	C₄₉H₄₄O₈	760.3031	9.49	741.2882	[M − H₂O − H]⁻^-	3.201
8HA	C₅₆H₅₀O₉	866.3449	9.73	847.3228	[M − H₂O − H]⁻	0.140
9HA	C₆₃H₅₆O₁₀	972.2868	9.76	953.3691	[M − H₂O − H]⁻	−0.447
10HA	C₇₀H₆₂O₁₁	1078.4287	9.85	1047.4118	[M − CH₂O − H]⁻	0.476
10HA	C₇₀H₆₂O₁₁	1078.4287	9.85	1059.4114	[M − H₂O − H]⁻	0.008