Table 3. Hydroperfluoroalkylation and Homologation via a 1,6-HAT/Migration Cascade^a.

^aReactions conducted on 0.2 mmol scales with perfluoroalkyl iodide (1.5 equiv) in CH₃CN (2 mL).

^bC₆F₁₃Br (1.5 equiv) used.

^cRun at 1 mmol scale.