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. 2021 Aug 2;9:692939. doi: 10.3389/fchem.2021.692939

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Copyright © 2021 Qiu, Cui, Ge, Kurmoo, Ma and Su.

This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.

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Solution state CVs of H₂L measured over 3 consecutive sweeps (A), solution state CVs of [Fe^ⅡL(CH₃OH)₂] measured over 3 consecutive sweeps (B), solid state CV for 1 obtained at 100 mVs⁻¹ over 3 consecutive scans (C), solid-state UV-vis-NIR spectroelectrochemistry of 1 at 0 V (black) and 1.30 V (red) (D). Gray spectra correspond to the spectral transition over the applied potential range of 1.00–1.30 V. Experiment performed in 0.1 mol L⁻¹ TBAPF₆ in CH₂Cl₂. Arrows denote the direction of forward scan.