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. 2021 Jun 29;12(8):1325–1351. doi: 10.1039/d1md00083g

Scheme 29. Synthesis of unprotected alkene-bridged cyclic peptides under aqueous conditions with AquaMet 73 as Ru-catalyst. AA = amino acid, X = H, Ac; Y = OH, NH2, Z = CH2, (CH2)3, CH2SCH2, PEPTIDE1 = 1 or 5 amino acids, PEPTIDE2 = 2 or 5 amino acids, PEPTIDE3 = 1 amino acid.

Scheme 29