TABLE 1.
No | Rt (Min) | Calculated (m/z) | Estimated (m/z) | Adducts | Error (ppm) | Elemental composition | MS/MS fragments (m/z) | Identifications |
---|---|---|---|---|---|---|---|---|
1 | 4.22 | 197.046 | 197.045 | [M-H]- | −4.43 | C9H10O5 | 197, 179, 135 | Danshensua |
2 | 4.69 | 353.088 | 353.088 | [M-H]- | −0.46 | C16H18O9 | 191, 179, 135 | Neochlorogenic acida |
3 | 5.21 | 353.088 | 353.088 | [M-H]- | −0.46 | C16H18O9 | 191, 179, 173 | Chlorogenic acida |
4 | 6.51 | 609.146 | 609.147 | [M-H]- | 0.61 | C27H30O16 | 301, 300 | Rutina |
5 | 6.78 | 463.088 | 463.088 | [M-H]- | 0.25 | C21H20O12 | 463, 300, 301 | Isoquercitrina |
6 | 7.07 | 193.051 | 193.050 | [M-H]- | −3.80 | C10H10O4 | 178, 149, 134 | Ferulic acida |
7 | 7.58 | 717.146 | 717.147 | [M-H]- | 1.63 | C36H30O16 | 339, 321, 295 | Salvianolic acid E |
8 | 7.9 | 609.183 | 609.183 | [M-H]- | 0.11 | C28H34O15 | 301 | Hesperidina |
9 | 7.99 | 359.077 | 359.077 | [M-H]- | −0.51 | C18H16O8 | 197, 179, 161 | Rosmarinic acida |
10 | 8.22 | 717.146 | 717.146 | [M-H]- | 1.71 | C36H30O16 | 339, 331 | Salvianolic acid B |
11 | 9.51 | 637.177 | 637.178 | [M + HCO2]- | 0.22 | C28H32O14 | 283 | Linarina |
Compared with the retention time (Rt) and mass spectral data of reference standards.