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. 2021 Aug 5;12:719602. doi: 10.3389/fphar.2021.719602

TABLE 1.

Phytochemicals of WEMA by UHPLC-MS/MS.

No Rt (Min) Calculated (m/z) Estimated (m/z) Adducts Error (ppm) Elemental composition MS/MS fragments (m/z) Identifications
1 4.22 197.046 197.045 [M-H]- −4.43 C9H10O5 197, 179, 135 Danshensua
2 4.69 353.088 353.088 [M-H]- −0.46 C16H18O9 191, 179, 135 Neochlorogenic acida
3 5.21 353.088 353.088 [M-H]- −0.46 C16H18O9 191, 179, 173 Chlorogenic acida
4 6.51 609.146 609.147 [M-H]- 0.61 C27H30O16 301, 300 Rutina
5 6.78 463.088 463.088 [M-H]- 0.25 C21H20O12 463, 300, 301 Isoquercitrina
6 7.07 193.051 193.050 [M-H]- −3.80 C10H10O4 178, 149, 134 Ferulic acida
7 7.58 717.146 717.147 [M-H]- 1.63 C36H30O16 339, 321, 295 Salvianolic acid E
8 7.9 609.183 609.183 [M-H]- 0.11 C28H34O15 301 Hesperidina
9 7.99 359.077 359.077 [M-H]- −0.51 C18H16O8 197, 179, 161 Rosmarinic acida
10 8.22 717.146 717.146 [M-H]- 1.71 C36H30O16 339, 331 Salvianolic acid B
11 9.51 637.177 637.178 [M + HCO2]- 0.22 C28H32O14 283 Linarina
a

Compared with the retention time (Rt) and mass spectral data of reference standards.