Table 1.
Overview of the most significant polymers with LCST behavior ordered by the polymer arrangements star polymer, polymer micelles as well as polymers covalently grafted on nanoparticles and flat surfaces.
Polymer arrangements | Polymer | Object of research/highlighted application | reference |
| |||
star polymers [102–103,106] | PNIPAAm-based polymers [102] | ||
PNIPAAm-PDEAEMA | synthesis/analysis | [141–142] | |
PNIPAAm-PS | synthesis/analysis | [143] | |
PNIPAAm-PEG | synthesis/analysis | [108] | |
PEG-PDEAEMA-PNIPAAm | synthesis/analysis | [144] | |
PEG-PNIPAAm-Plys/PAA | synthesis/analysis | [145] | |
PS-PCL-PNIPAA | synthesis/analysis | [146] | |
PEG-PtBMA-PNIPAAm | synthesis/analysis | [147] | |
PS-PNIPAAm-PDMAEMA | synthesis/analysis | [148] | |
PNIPAAm-P4VP | synthesis/analysis | [149] | |
PS-PNIPAAm-P4VP | synthesis/analysis | [102,149] | |
PAA-PNIPAAm | nanocarrier/molecule delivery; synthesis | [105] | |
PCL-PNIPAAm | nanocarrier/drug delivery, synthesis | [150] | |
PTEGDA-PNIPAAm-PNMA | drug delivery, synthesis | [151] | |
PNASME-PNIPAAm | synthesis/analysis | [152] | |
POX-based star polymers | |||
PBOX-PEtOX | synthesis/analysis | [153] | |
PEtOX- PIPOX | synthesis/analysis | [154] | |
PIPOX | synthesis/analysis | [155–156] | |
PEG or PEG derivates-based star polymers | |||
PEG-PDMAEMA | synthesis/analysis | [157] | |
PCL-POEOMA-PMEO2M | synthesis/analysis | [158] | |
PDEGA-PHEA | synthesis/analysis | [159] | |
P(DEGMA-OEGMA-GMA) | as nanolayers for controlled cell sheet detachment, synthesis | [160] | |
PDMAEMA-PDEGA | synthesis/analysis | [161] | |
other polymers | |||
MPEP-PCL-PPE | synthesis/analysis | [162] | |
PVAc-PNVCL-PNVP | synthesis/analysis | [163] | |
| |||
polymer micelles [4,59,164–165] | PNIPAAm-based micelles | ||
P4VP-PNIPAAm | catalysis, synthesis | [166] | |
PNIPAAm-PDMAAm | drug delivery, synthesis | [167] | |
PNIPAAm-DNA | synthesis/analysis | [168] | |
PNIPAAm-PHPMA-PEG | synthesis/analysis | [169] | |
PNIPAAm-PBMA | drug delivery, synthesis | [170] | |
PNIPAAm-PS | synthesis/analysis | [171–172] | |
PNIPAAm-HPG | [173] | ||
POX-based micelles [174–175] | |||
PEtOX-PPropOX | synthesis/analysis | [176] | |
PIPOX-PAMPT | radionuclide delivery, synthesis | [177] | |
PMeOX-PIPOX-PBuO | synthesis/analysis | [178] | |
PBOX-PEtOX | drug delivery, synthesis | [153] | |
PMeOX-PBuOX | synthesis/analysis | [179] | |
other polymers | |||
PDMAEMA-PCL | drug delivery, synthesis | [180] | |
PEGMA-PMMA-PDEAEMA | synthesis/analysis | [181] | |
PHPMA-PDEGMA | drug delivery, synthesis | [182] | |
| |||
polymers grafted on nanoparticles [4,115,117,164,183–185] | PNIPAAm-based grafted nanoparticles | ||
PNIPAAm- | preparation/analysis | [186] | |
PDMAAm@Fe3O4 | preparation/analysis | [187] | |
PNIPAAm-PNHMA@ Fe3O4 | drug release, preparation | [188–191] | |
PNIPAAm@SiO2 | molecule delivery, preparation | [191–194] | |
PNIPAAm@Fe3O4 | microfluidic separation and assay; sensing; drug release, preparation | [195–201] | |
PNIPAAm@Au | fundamental investigation, preparation, cell up-take control | [200,202] | |
PNIPAAm-PAm@Au PNIPAAm-PNVP@Fe3O4 | cell up-take control drug delivery/cell separation, preparation | [203] | |
PNIPAAm-PDMAEMA@Fe3O4/Au | catalysis, preparation | [204] | |
PNIPAAm-PAA@UCNP | sensing, preparation | [205] | |
PNIPAAm-PMAA-PVP@Fe2O3 | drug delivery, preparation | [206] | |
POX-based grafted nanoparticles [207] | |||
PIPOX@Fe3O4 | preparation/analysis | [208] | |
PIPOX-PEtOX@SPION | cell up-take control | [209] | |
PEtOX/PPropOX-PVIm/P4VP@Ag | preparation/analysis | [210] | |
PEG or PEG derivates-based grafted nanoparticles [211] | |||
PEG-PDMAEMA@Au | preparation/analysis | [212] | |
PEGMA@Au | preparation/analysis | [151,213] | |
PMEO2MA-OEGMA@Au | protein adsorption, preparation | [214] | |
PEGMA-PEG@SiO2 | catalysis, preparation | [215] | |
PEG-PPO@SPIO | protein adsorption, preparation sensing, contrast agent |
[216] | |
PEG-PPO@ SiO2 | drug delivery | [217] | |
other polymers | |||
P(HPEI-IBAm)@Au | preparation/analysis | [218–219] | |
PVME@Au | preparation/analysis | [220] | |
PMDM@Au, glass or SiO2 | catalysis, sensing, preparation | [221–223] | |
PTEGMMA-PMAPMA@SiO2 | protein adsorption, preparation | [224] | |
| |||
polymers grafted on flat surfaces [3,43,225–226] | PNIPAAm-based grafted surface [43,227] | ||
PNIPAAm@different flat substrates, such as Au, Si-wafers, glass | preparation, theory, fundamental investigation of swelling behavior, cell/protein adhesion, sensing, environmental application | [132,228–255] | |
PNIPAAm-PAA@SiO2 | protein adhesion, preparation | [256–259] | |
PMMA-PBIEM-PNIPAAm | cell up-take control, preparation | [260] | |
PNIPAAm-PLAMA@glass | preparation | [261] | |
PNIPAAm-PDMAEMA@Al | preparatio | [262] | |
PNIPAAm-PNTBA@glass | cell up-take control, preparation | [263] | |
PNIPAAm-ODS@glass | microfluidic, preparation | [264] | |
PNIPAAm-PEG@Au | cell up-take control, preparation | [265] | |
POX-based grafted surface | |||
PCPOX-PMeOX@SiO2 | preparation | [228] | |
PPropOX@glass | cell up-take control, preparation | [266] | |
PEG or PEG derivates-based grafted surfaces [43,211] | |||
PMEO2MA-PDEAEMA@SiO2 | preparation | [267] | |
PMEO2MA-POEGMA@SiO2 | protein adsorption, preparation | [268] | |
other polymers | |||
PMDM@glass | protein adsorption, preparation | [221] | |
PVCL-PDMAEMA-PMPC@PDMS | controlled wettability self-cleaning, anti-microbial coating, preparation |
[269] |