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. 2021 Jul 26;12(33):11121–11129. doi: 10.1039/d1sc03050g

The 16 energy eigenvectors of the Hubbard Hamiltonian for charge states N − 4 to N and their designation, under the assumption of equal site energies. σ = (↑,↓), ΦA = |↑↓,0〉, ΦB = |0,↑↓〉, ΦC = |↑,↓〉 and ΦD = |↓,↑〉. The coefficients c+ and c depend on the values of t, U, and V, as described in the text.

Charge state Eigenstates of HHB State (degeneracy)
N − 4 |0,0〉 SN−4 (1)
N − 3 graphic file with name d1sc03050g-t4.jpg D+,σN−3 (2)
graphic file with name d1sc03050g-t5.jpg D−,σN−3 (2)
N − 2 c(ΦA + ΦB) − c+(ΦCΦD) SN−2, (1)
graphic file with name d1sc03050g-t6.jpg T0N−2, T1N−2T−1N−2 (3)
graphic file with name d1sc03050g-t7.jpg SCSN−2, (1)
c+(ΦA + ΦB) + c(ΦC + ΦD) S+N−2, (1)
N − 1 graphic file with name d1sc03050g-t8.jpg D+,σN−1, (2)
graphic file with name d1sc03050g-t9.jpg D−,σN−1, (2)
N |↑↓,↑↓〉 SN, (1)