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. 2021 Aug 12;6(33):21339–21349. doi: 10.1021/acsomega.1c01588

Table 4. Parameter fits of Models of Langmuir, Freundlich, Redlich–Peterson, and Sips to Experimental Data of Caffeine Adsorption.

caffeine
two-parameter models
  Langmuir model
Freundlich model
sample Qo (mg g–1) KL (mL mg–1) R2 KF (mL g–1) 1/n R2
SBA-15 6.94 30.3 0.510 6.92 0.0003 0.510
SBA-15-NH2 4.45 0.029 0.856 0.4288 0.4609 0.860
three-parameter models
  Redlich–Peterson model
Sips Model
sample KRP (mg g–1) αRP (mL mg–1) β R2 Qo (mg g–1) KS (mL mg–1) 1/ns R2
SBA-15 4.84 0.424 1.14 0.510 18.6 6.32 × 10–7 0.0449 0.509
SBA-15-NH2 1.35 0.001 1.16 0.999 22.5 0.0004 0.5182 0.858