Table 2.

Secondary metabolites identified in ethanol extract of blackberry fruits (EB) and in ethanol extract of almond skin (ET) by LC-ESI/LTQOrbitrap/MS/MSn analysis.

N°	Rt	Molecular Formula	Identity	EB	ET
1	1.81	C12 H20 O10	agarobiose	x	x
2	4.78	C7 H10 O7	citric acid methyl ester	x
3	5.54	C9 H17 O5 N	pantothenic acid		x
4	6.8	C34 H24 O22	pedunculagin	x
5	7.17	C41 H28 O27	geranin	x
6	7.22	C16 H18 O9	chlorogenic acid	x
7	7.4	C27 H31 O16+	cyanidin dihexoside	x
8	7.72	C27 H22 O18	galloyl HHDP glucose	x
9	7.81	C30H26O12	EC-b-EC		x
10	7.94	C22 H22 O13	laricitrin glucoside	x
11	7.98	C21 H21 O11+	cyanidin 3-O-glucoside	x
12	8.56	C21 H21 O10+	pelargonidin 3-O-glucoside	x
13	8.86	C20H27NO11	amygdalin		x
14	8.86	C15H14O6	(+)-catechin		x
15	8.86	C45H38O18	EC-b-EC-b-EC		x
16	8.88	C21 H22 O12	dihydroquercetin glucoside	x	x
17	8.93	C20 H19 O10+	cyanidin xyloside	x
18	9.13	C24 H22 O14	kaempferol malonyl glucoside	x
19	9.27	C30H27O12	EC-b-EC		x
20	9.37	C20 H20 O11	dihydroquercetin pentoside	x
21	9.42	C27 H28 O15	cyanidin dioxalyl glucoside	x
22	9.83	C15H14O6	(-)-epicatechin		x
23	10.16	C45H38O18	EC-b-EC-b-EC		x
24	10.25	C45H36O18	EC-b-EC-a-EC		x
25	10.52	C41 H26 O26	castalagin	x
26	10.74	C20 H16 O12	quercetin 3-O- rhamnoside	x	x
27	10.81	C21 H16 O14	methyl ellagic acid glucuronide	x	x
28	11.43	C30H24O12	EC-a-EC		x
29	11.47	C41 H28 O26	galloyl bis HHDP glucose	x
30	11.52	C21 H21 O12+	delphinidin 3-O-glucoside	x
31	11.59	C21 H22 O11	eriodictyol-7-O-glucoside		x
32	11.61	C21 H20 O12	quercetin 3-O-glucoside	x	x
33	11.68	C21 H20 O11	kaempferol 3-O-glucoside	x	x
34	11.77	C21 H18 O13	quercetin glucuronide	x
35	11.81	C28H32O16	isorhamnetin rutinoside		x
36	11.85	C27H30O15	kaempferol 3-O-rutinoside	x	x
37	11.95	C26 H34 O11	icariside E5		x
38	12.01	C27 H18 O16	quercetin hydroxy-methylglutaroy-gluc	x
39	12.48	C22H22O12	isorhamnetin glucoside	x	x
40	12.92	C21 H22 O10	prunin		x
41	13.02	C22 H20 O13	isorhamnetin glucuronide		x
42	13.02	C21 H20 O12	iperoside	x	x
43	13.06	C37 H60 O13	unknown	x
44	13.06	C42 H54 O9	unknown	x
45	13.21	C30 H38 O10	sesquimarocanol B		x
46	13.41	C36 H56 O12	suavissimoside f 1	x
47	13.68	C18 H16 O8	rosmarinic acid		x
48	13.91	C20 H22 O8	piceid		x
49	15.26	C30 H18 O14	unknown	x
50	15.88	C18 H32 O5	9,12,13-TriHODE (10, 15)		x
51	16.16	C72 H110 O24	coreanoside F1	x
52	16.27	C21 H40 O7	unknown		x
53	16.55	C15 H10 O7	quercetin	x
54	17.54	C30 H46 O8	trachelosperogenin C	x
55	17.77	C18 H34 O5	9,12,13-TriHOME (10)		x
56	18.56	C30 H48 O6	19α-hydroxyasiatic acid	x
57	20.3	C30 H46 O7	corosin	x
58	26.02	C60 H90 O14	coreanogenoic acid	x
59	17.33	C30 H46 O6	3-epiilexgenin A	x