Table 1. Chemical Shifts, Relative Assignments, and Functional Groups of the 14 Selected Carbon Signals.
δ (ppm)a | carbon atom | functional group | |
---|---|---|---|
1 | 14.390 | L18 | –CH3 |
2 | 14.433 | O18 | –CH3 |
3 | 128.204 | L12, sn-2′ | ω-6, −CH=CH– |
4 | 128.216 | L12, sn-1′, 3′ | ω-6, −CH=CH– |
5 | 128.383 | L10, sn-1′, 3′ | ω-9, −CH=CH– |
6 | 128.401 | L10, sn-2′ | ω-9, −CH=CH– |
7 | 129.994 | O9, sn-2′ | ω-9, −CH=CH– |
8 | 130.021 | O9, sn-1′, 3′ | ω-9, −CH=CH– |
9 | 130.285 | L9, sn-2′ | ω-9, −CH=CH– |
10 | 130.312 | L9, sn-1′, 3′ | ω-9, −CH=CH– |
11 | 130.523 | L13, sn-1′, 3′ | ω-6, −CH=CH– |
12 | 173.142 | L1, sn-2′ | –CH2–OOC–CH2– |
13 | 173.552 | L1, sn-1′, 3′ | –CH2–OOC–CH2– |
14 | 173.595 | P1, sn-1′, 3′ | –CH2–OOC–CH2– |
Chemical shifts are reported with respect to TMS. L, linoleic acid; O, oleic acid; P, palmitic acid in triglycerides.