. 2021 Jul 19;60(15):11530–11547. doi: 10.1021/acs.inorgchem.1c01550

Table 7. Cathodic Peak Potential (E_pc), Anodic Peak Potential (E_pa), and Half-wave Potential (E_1/2) for Copper Complexes of DO4S, DO3S, and DO2A2S in Aqueous Solution at pH 7, I = 0.15 mol/L NaNO₃, and T = 25 °C.

complex	E_pc [V] vs SCE^a	E_pa [V] vs SCE^a	ΔE_p [V] vs SCE^a	E_1/2 [V] vs SCE^a
Cu-DO4S	–0.182 ± 0.001	–0.115 ± 0.003	0.067	–0.149 ± 0.001
Cu-DO3S	–0.334 ± 0.004	–0.252 ± 0.003	0.082	–0.293 ± 0.005
Cu-DO2A2S	–0.496^b	–0.341^b	0.155^b	–0.421 ± 0.004

Average of the values measured at 0.01 V/s ≤ v ≤ 0.2 V/s.

Value at v = 0.01 V/s.

Table 7. Cathodic Peak Potential (Epc), Anodic Peak Potential (Epa), and Half-wave Potential (E1/2) for Copper Complexes of DO4S, DO3S, and DO2A2S in Aqueous Solution at pH 7, I = 0.15 mol/L NaNO3, and T = 25 °C.