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. 2021 Aug 3;125(31):8797–8804. doi: 10.1021/acs.jpcb.1c04551

Table 1. Reaction Rate and Estimated Arrhenius Parameters of the TaHeR–Hydroxylamine (0.5 M) Reaction at Various Temperatures in the Absence and Presence of Light.

  dark
light
temperature (°C) k (s–1) Ead (kcal·mol–1) A (s–1) k (s–1) Eal (kcal·mol–1) A (s–1)
12 (1.9 ± 0.1) × 10–3 14.41 ± 0.1 (2.0 ± 0.07) × 108 (3.2 ± 0.1) × 10–3 15.50 ± 0.09 (2.5 ± 0.07) × 109
17 (2.7 ± 0.08) × 10–3 (4.8 ± 0.07) × 10–3
22 (4.2 ± 0.06) × 10–3 (6.7 ± 0.05) × 10–3
27 (6.8 ± 0.06) × 10–3 (1.0 ± 0.05) × 10–2
32 (9.9 ± 0.06) × 10–3 (1.9 ± 0.06) × 10–2
37 (1.4 ± 0.1) × 10–2 (2.9 ± 0.1) × 10–2