Table 1. Reaction Rate and Estimated Arrhenius Parameters of the TaHeR–Hydroxylamine (0.5 M) Reaction at Various Temperatures in the Absence and Presence of Light.
| dark |
light |
|||||
|---|---|---|---|---|---|---|
| temperature (°C) | k (s–1) | Ead (kcal·mol–1) | A (s–1) | k (s–1) | Eal (kcal·mol–1) | A (s–1) |
| 12 | (1.9 ± 0.1) × 10–3 | 14.41 ± 0.1 | (2.0 ± 0.07) × 108 | (3.2 ± 0.1) × 10–3 | 15.50 ± 0.09 | (2.5 ± 0.07) × 109 |
| 17 | (2.7 ± 0.08) × 10–3 | (4.8 ± 0.07) × 10–3 | ||||
| 22 | (4.2 ± 0.06) × 10–3 | (6.7 ± 0.05) × 10–3 | ||||
| 27 | (6.8 ± 0.06) × 10–3 | (1.0 ± 0.05) × 10–2 | ||||
| 32 | (9.9 ± 0.06) × 10–3 | (1.9 ± 0.06) × 10–2 | ||||
| 37 | (1.4 ± 0.1) × 10–2 | (2.9 ± 0.1) × 10–2 | ||||