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. 2021 Jul 28;37(31):9478–9489. doi: 10.1021/acs.langmuir.1c01295

Table 2. E-PABA Steady-State Flux across the Model Membranes, the LPP Repeat Distance, the Midpoint Temperatures of the Orthorhombic–Hexagonal Phase Transition (TM,OR-HEX), the Ratio of the 730–720 cm–1 Rocking Peak Intensity, and the Length of the δCD2 Mode Peak Splitting (cm–1)a.

lipid model (fully protiated) steady-state flux (μg/cm2/h) LPP repeat distance (nm) TM,OR-HEX (°C) 730:720 cm–1 peak intensity ratio (10 °C) 730:720 cm–1 peak intensity ratio (32 °C) δCD2 mode peak splitting distance (cm–1)
NS(C16)-0 2.7 ± 1.1 12.7 ± 0.0 35.6 ± 1.1 0.67 ± 0.08 0.53 ± 0.07 3.4 ± 0.2
NS(C16)-25 7.3 ± 1.0 12.8 ± 0.1 37.2 ± 1.2 0.53 ± 0.08 0.40 ± 0.10 4.1 ± 0.2
NS(C16)-50 9.9 ± 2.9 13.0 ± 0.0 38.9 ± 0.5 0.48 ± 0.14 0.36 ± 0.17 4.5 ± 0.2
NS (C16)-75 16.3 ± 4.4 13.5 ± 0.0 39.1 ± 1.3 0.44 ± 0.06 0.30 ± 0.12 6.7 ± 0.5
FA(C24)       0.92 ± 0.05    
a

The δCD2 mode’s peak splitting distance was obtained from the counterparts of the fully protiated models with the FA chains deuterated (−DFA). The error was calculated as the SD.