Table 2. E-PABA Steady-State Flux across the Model Membranes, the LPP Repeat Distance, the Midpoint Temperatures of the Orthorhombic–Hexagonal Phase Transition (TM,OR-HEX), the Ratio of the 730–720 cm–1 Rocking Peak Intensity, and the Length of the δCD2 Mode Peak Splitting (cm–1)a.
| lipid model (fully protiated) | steady-state flux (μg/cm2/h) | LPP repeat distance (nm) | TM,OR-HEX (°C) | 730:720 cm–1 peak intensity ratio (10 °C) | 730:720 cm–1 peak intensity ratio (32 °C) | δCD2 mode peak splitting distance (cm–1) |
|---|---|---|---|---|---|---|
| NS(C16)-0 | 2.7 ± 1.1 | 12.7 ± 0.0 | 35.6 ± 1.1 | 0.67 ± 0.08 | 0.53 ± 0.07 | 3.4 ± 0.2 |
| NS(C16)-25 | 7.3 ± 1.0 | 12.8 ± 0.1 | 37.2 ± 1.2 | 0.53 ± 0.08 | 0.40 ± 0.10 | 4.1 ± 0.2 |
| NS(C16)-50 | 9.9 ± 2.9 | 13.0 ± 0.0 | 38.9 ± 0.5 | 0.48 ± 0.14 | 0.36 ± 0.17 | 4.5 ± 0.2 |
| NS (C16)-75 | 16.3 ± 4.4 | 13.5 ± 0.0 | 39.1 ± 1.3 | 0.44 ± 0.06 | 0.30 ± 0.12 | 6.7 ± 0.5 |
| FA(C24) | 0.92 ± 0.05 |
The δCD2 mode’s peak splitting distance was obtained from the counterparts of the fully protiated models with the FA chains deuterated (−DFA). The error was calculated as the SD.