Table 1. Summary of Lifetime Data for 2-Crypt, 3-Crypt, 5, and 7a.
| complex | λex (nm) | λem (nm) | τ1 (μs)/(%) | τ2 (μs)/(%) | τ3 (μs)/(%) | χ2 |
|---|---|---|---|---|---|---|
| 2-cryptb | 250 | 550 | 5.9 | 40.8 | 176.7 | 1.6 |
| (34) | (37) | (27) | ||||
| 3-cryptb | 280 | 320 | 3.7 | 24.0 | 186.4 | 1.3 |
| (56) | (44) | (29) | ||||
| 280 | 360 | 4.3 | 77.5 | 153.3 | 1.2 | |
| (12) | (51) | (36) | ||||
| 280 | 492 | 5.2 | 41.2 | 204.1 | 1.0 | |
| (11) | (31) | (58) | ||||
| 280 | 580 | 6.9 | 44.2 | 198.7 | 1.3 | |
| (11) | (36) | (53) | ||||
| 3-cryptc | 300 | 420 | 1.7 | 7.1 | – | 1.2 |
| (47) | (53) | |||||
| 300 | 475 | 1.02 | 8.22 | – | 1.3 | |
| (25) | (75) | |||||
| 5b | 230 | 370 | 109.5 | – | – | 1.3 |
| (100) | ||||||
| 230 | 440 | 130.1 | – | – | 1.2 | |
| (100) | ||||||
| 230 | 550 | 5.2 | 57.4 | 160.5 | 1.0 | |
| (1) | (9) | (90) | ||||
| 5c | 260 | 430 | 1.0 | 8.2 | – | 2.1 |
| (22) | (78) | |||||
| 260 | 535 | 55.1 | 148.0 | – | 1.1 | |
| (28) | (72) | |||||
| 260 | 590 | 51.9 | 139.2 | – | 1.3 | |
| (27) | (73) | |||||
| 7c | 325 | 480 | 11.0 | 102.9 | – | 1.1 |
| (10) | (90) | |||||
| 325 | 550 | 45.6 | 202.5 | – | 1.2 | |
| (78) | (32) |
Estimated error ± 10%.
Sample measured at 295 K in the solid state.
Sample measured at 77 K in a frozen 2-Me-thf glass.