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Optical spectra of the closed-shell states of Ag158Pd43 NPs with different chemical orderings: L11—layered; qL11—almost (quasi) layered; LEH—the low-energy homotop; and PdS—one Pd atom moved on the surface from inside. The intensity is given in oscillatory strength (f), while X, Y, and Z refer to the three components of the electric dipole transition moment.
