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. 2021 Jul 21;37(30):9069–9077. doi: 10.1021/acs.langmuir.1c01108

Table 2. Top: Bragg Peak and Rod Positions and the Corresponding Full Widths at Half-Maximum of Racemic and Enantiomeric N-C16-Serine (2 mN/m), N-C16-Serine-ME (dl: 15 mN/m and l: 17 mN/m), and N-C18-Threonine-ME (15 mN/m) Monolayersa.

compound Qxy–1) Qz–1) Qxy–1) Qz–1) Qxy–1) Qz–1)
N-C16-dl-serine     1.152 1.16 1.400 0.58
      0.024 0.31 0.009 0.29
N-C16-l-serine 0.834 1.33 1.267 0.41 1.485 0.92
  0.044 0.30 0.009 0.30 0.020 0.30
N-C16-dl-serine-ME 1.099 1.109 1.323 0.41 1.490 0.68
  0.040 0.3 0.009 0.28 0.017 0.29
N-C16-l-serine-ME 1.108 1.12 1.325 0.42 1.504 0.70
  0.034 0.30 0.008 0.28 0.013 0.29
N-C18-dl-threonine-ME     0.981 1.16 1.364 0.58
      0.045 0.27 0.014 0.28
N-C18-l-threonine-ME 0.979 1.15 1.340 0.49 1.402 0.66
  0.042 0.28 0.013 0.27 0.017 0.28
compound a, b, c (Å) α, β, γ (deg) d t (deg) Axy2) A02)
N-C16-dl-serine 4.924 131.4 0.2412 45.2 26.9 18.9
  5.984 114.3        
  5.984 114.3        
N-C16-l-serine 4.964 145.9 0.5844 58.2 37.4 19.7
  7.542 121.5        
  8.839 92.6        
N-C16-dl-serine-ME 4.910 134.5 0.3389 44.8 28.1 19.9
  5.911 120.8        
  6.657 104.7        
N-C16-l-serine-ME 4.892 134.4 0.3416 45.4 27.7 19.5
  5.850 121.4        
  6.640 104.2        
N-C18-dl-threonine-ME 4.937 137.8 0.3835 49.8 31.6 20.4
  6.864 111.1        
  6.864 111.1        
N-C18-l-threonine-ME 4.916 138.2 0.3957 49.6 31.5 20.4
  6.729 114.3        
  7.040 107.5        
a

Bottom: Corresponding lattice parameters of racemic and enantiomeric N-C16-serine, N-C16-serine-ME, and N-C18-threonine-ME monolayers. a, b, c, and α, β, γ are the lattice parameters of the unit cell; t is the polar tilt angle; Axy is the molecular area; A0 is the cross-sectional area of the alkyl chain; and d is the lattice distortion.