Table 2. Top: Bragg Peak and Rod Positions and the Corresponding Full Widths at Half-Maximum of Racemic and Enantiomeric N-C16-Serine (2 mN/m), N-C16-Serine-ME (dl: 15 mN/m and l: 17 mN/m), and N-C18-Threonine-ME (15 mN/m) Monolayersa.
compound | Qxy (Å–1) | Qz (Å–1) | Qxy (Å–1) | Qz (Å–1) | Qxy (Å–1) | Qz (Å–1) |
---|---|---|---|---|---|---|
N-C16-dl-serine | 1.152 | 1.16 | 1.400 | 0.58 | ||
0.024 | 0.31 | 0.009 | 0.29 | |||
N-C16-l-serine | 0.834 | 1.33 | 1.267 | 0.41 | 1.485 | 0.92 |
0.044 | 0.30 | 0.009 | 0.30 | 0.020 | 0.30 | |
N-C16-dl-serine-ME | 1.099 | 1.109 | 1.323 | 0.41 | 1.490 | 0.68 |
0.040 | 0.3 | 0.009 | 0.28 | 0.017 | 0.29 | |
N-C16-l-serine-ME | 1.108 | 1.12 | 1.325 | 0.42 | 1.504 | 0.70 |
0.034 | 0.30 | 0.008 | 0.28 | 0.013 | 0.29 | |
N-C18-dl-threonine-ME | 0.981 | 1.16 | 1.364 | 0.58 | ||
0.045 | 0.27 | 0.014 | 0.28 | |||
N-C18-l-threonine-ME | 0.979 | 1.15 | 1.340 | 0.49 | 1.402 | 0.66 |
0.042 | 0.28 | 0.013 | 0.27 | 0.017 | 0.28 |
compound | a, b, c (Å) | α, β, γ (deg) | d | t (deg) | Axy (Å2) | A0 (Å2) |
---|---|---|---|---|---|---|
N-C16-dl-serine | 4.924 | 131.4 | 0.2412 | 45.2 | 26.9 | 18.9 |
5.984 | 114.3 | |||||
5.984 | 114.3 | |||||
N-C16-l-serine | 4.964 | 145.9 | 0.5844 | 58.2 | 37.4 | 19.7 |
7.542 | 121.5 | |||||
8.839 | 92.6 | |||||
N-C16-dl-serine-ME | 4.910 | 134.5 | 0.3389 | 44.8 | 28.1 | 19.9 |
5.911 | 120.8 | |||||
6.657 | 104.7 | |||||
N-C16-l-serine-ME | 4.892 | 134.4 | 0.3416 | 45.4 | 27.7 | 19.5 |
5.850 | 121.4 | |||||
6.640 | 104.2 | |||||
N-C18-dl-threonine-ME | 4.937 | 137.8 | 0.3835 | 49.8 | 31.6 | 20.4 |
6.864 | 111.1 | |||||
6.864 | 111.1 | |||||
N-C18-l-threonine-ME | 4.916 | 138.2 | 0.3957 | 49.6 | 31.5 | 20.4 |
6.729 | 114.3 | |||||
7.040 | 107.5 |
Bottom: Corresponding lattice parameters of racemic and enantiomeric N-C16-serine, N-C16-serine-ME, and N-C18-threonine-ME monolayers. a, b, c, and α, β, γ are the lattice parameters of the unit cell; t is the polar tilt angle; Axy is the molecular area; A0 is the cross-sectional area of the alkyl chain; and d is the lattice distortion.