Table 5.
Position | 1 | 2 (2’S) | 2 (2’R) | 3 |
---|---|---|---|---|
δC, Type | ||||
1 | 170.2, C | 171.3, C | 172.8, C | 170.6, C |
2 | 91.1, C | 89.2, C | 91.3, C | 90.5, C |
3 | 44.0, CH | 48.2, CH | 47.0, CH | 54.1, CH |
4 | 37.8, CH | 36.7, CH | 35.9, CH | 47.4, CH |
5 | 169.9, C | 165.3, C | 165.1, C | 174.3, C |
7 | 157.2, C | 159.2, C | 159.2, C | 157.4, C |
8 | 108.5, CH | 110.7, CH | 110.7, CH | 108.9, CH |
9 | 147.2, C | 145.4, C | 145.2, C | 147.0, C |
10 | 113.0, CH | 108.3, CH | 108.4, CH | 112.7, CH |
11 | 160.8, C | 160.0, C | 160.0, C | 160.6, C |
12 | 108.7, C | 112.7, C | 112.8, C | 108.7, C |
13 | 179.2, C | 173.8, C | 173.7, C | 179.6, C |
14 | 118.5, C | 121.9, C | 121.2, C | 117.0, C |
15 | 22.2, CH3 | 22.1, CH3 | 22.1, CH3 | 22.2, CH3 |
16 | 53.3, CH3 | 53.0, CH3 | 53.5, CH3 | 53.4, CH3 |
1′ | 168.2, C | 170.0, C | 167.5, C | 167.6, C |
2′ | 107.9, C | 104.6, C | 105.9, C | 107.6, C |
3′ | 43.3, CH | 43.2, CH | 48.3, CH | 42.3, CH |
4′ | 25.4, CH2 | 26.3, CH2 | 27.5, CH2 | 25.5, CH2 |
5′ | 165.4, C | 166.7, C | 166.1, C | 165.1, C |
7′ | 155.9, C | 156.1, C | 156.1, C | 155.1, C |
8′ | 107.4, CH | 107.5, CH | 107.6, CH | 106.8, CH |
9′ | 147.4, C | 147.4, C | 147.5, C | 147.3, C |
10′ | 112.3, CH | 112.6, CH | 112.6, CH | 112.0, CH |
11′ | 160.3, C | 160.5, C | 160.5, C | 160.8, C |
12′ | 108.3, C | 108.5, C | 108.5, C | 108.7, C |
13′ | 180.5, C | 179.9, C | 179.8, C | 181.3, C |
14′ | 111.3, C | 112.7, C | 112.4, C | 114.8, C |
15′ | 22.4, CH3 | 22.4, CH3 | 22.4, CH3 | 22.3, CH3 |
16′ | 52.9, CH3 | 53.2, CH3 | 52.9, CH3 | 52.9, CH3 |
11-OMe | - | 56.3, CH3 | 56.3, CH3 | - |
4-Me | - | - | - | 28.4, CH3 |
2′-OMe | 52.3, CH3 | - | - | 51.3, CH3 |