Skip to main content
. Author manuscript; available in PMC: 2022 Aug 4.
Published in final edited form as: J Am Chem Soc. 2021 Jul 22;143(30):11670–11678. doi: 10.1021/jacs.1c04968

Scheme 3. Mechanistic Studies on Co(II)-Catalyzed 1,4-C–H Alkylation of α-Aryldiazoketones.

Scheme 3.

aFree energy profile of the [Co(P5)]-catalyzed 1,4-C–H alkylation. Density functional theory calculations were performed at SMD(diisopropylether)-BP86-D3(BJ)/def2TZVPP//BP86-D3(BJ)/def2SVP level of theory.