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. 2021 Aug 18;11(8):2101. doi: 10.3390/nano11082101

Table 2.

Base screening of the N-formylation of amine 1.

graphic file with name nanomaterials-11-02101-i002.jpg

Entry Base Yield 2 Entry Base Yield 2
1 - 14 6 K2CO3 54
2 LiOH·H2O 60 7 Cs2CO3 69
3 NaOH 65 8 KOt Bu 69
4 KOH 75 9 K3PO4 60
5 CsOH·H2O 91 10 CsF 39

1 Reaction conditions: 1a (0.20 mmol), AuPd–Fe3O4 (1.4 mol%), base (3.0 equiv), O2 (1.0 atm), methanol (1.0 mL), r. t., 18 h. 2 Determined from 1H NMR spectral analysis through the use of mesitylene as an internal standard.